Abstract
The concentration dependences of the relative viscosity of epoxy-4,4'-isopropylidenediphenol (Epikot 1009, E-05) and phenol-formaldehyde (DFFr) resins in Cellosolve solutions in the concentration range c = 5-60%, as well as the kinetics of thermal precondensation of a mixture of E-05 and DPFr resins in solution at molar ratios N 1/N 2 = 0.6-1.5, were studied by the method of capillary viscometry. The cluster structure of the surface of coatings on the metal sheet formed by cross-linked epoxy-phenol polymer in various kinetic stages of precondensation of the mixture of E-05 and DFFr resins in solution was studied by electron microscopy with gold decoration. The optimal concentrations of resins in solution and the precondensation kinetics of oligomer mixtures essential for formulating the compounds were calculated.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Markevich, M.A., Kuzaev, A. I., Vladimirov, L.V., et al., Vysokomol. Soedin., Ser. A, 1985, vol. 27, no. 5, pp. 1000-1008.
Kurmakova, I.N., Amfiteatrova, T.A., Kabanov, N.M., et al., Vysokomol. Soedin., Ser. B, 1985, vol. 27, no. 12, pp. 906-909.
Krasovskii, A.N., Polyakov, D.N., Baranov, V.G., and Mnatsakanov, S.S., Vysokomol. Soedin., Ser. A, 1991, vol. 33, no. 6, pp. 1221-1227.
Kurmakova, I.N., Trifonova, Yu.F., Ivanov, A.I., et al., Vysokomol. Soedin., Ser. B, 1988, vol. 30, no. 1, pp. 5-7.
Sukhareva, L.A., Sorokin, M.F., Kochnova, Z.A., et al., Lakokras. Mater. Ikh Primen., 1982, no. 4, pp. 30-31.
Sukhareva, L.A., Sorokin, M.F., Kochnova, Z.A., and Svetlakova, T.N., Lakokras. Mater. Ikh Primen., 1982, no. 1, pp. 10-11.
Tsvetkov, B.N., Eskin, V.E., and Frenkel, S.Ya., Struktura makromolekul v rastvorakh (Structure of Macromolecules in Solutions), Moscow: Nauka, 1964.
Markevich, M.A., Structural and Kinetic Aspects of the Processes of Formation of Epoxy-4,4▮-Isopropylidenediphenol Oligomers and 3D Polymers Thereof, Doctoral Dissertation, Chernogolovka, 1986.
Krasovskii, A.N., Krasheninnikov, V.A., and Kharlampiev, A.A., Vysokomol. Soedin., Ser. A, 1997, vol. 39, no. 2, pp. 250-258.
Markevich, M.A., Vladimirov, L.V., Prut, E.V., and Enikolopyan, N.S., Mekh. Kompoz. Mater., 1985, no. 1, pp. 25-28.
Krasovskii, A.N., Novikov, D.V., Krasheninnikov, V.A., et al., Zh. Prikl. Khim., 2001, vol. 74, no. 1, pp. 124134.
Nizhnik, I.N., Aleksandrov, V.N., Fartunin, V.I., and Rozenberg, B.A., Lakokras. Mater. Ikh Primen., 1989, no. 2, pp. 16-18.
Feder, J., Fractals, New York: Plenum, 1988.
Gennes, P.-G. de, Scaling Concepts in Polymer Physics, Ithaca: Cornell Univ., 1979.
Lakokrasochnye materialy dlya zashchity konservnoi tary (Paint and Varnish Materials for Can Protection), Lyalyushko, S.M., Ed., Moscow: NIITEKhim, 1981.
Gorshkov, A.V., Verenish, S.S., Evreinov, V.V., and Entelis, S.G., Chromatographia, 1988, vol. 26, pp. 338-342.
Krasovskii, A.N. and Novikov, D.V., Zh. Prikl. Khim., 1999, vol. 72, no. 9, pp. 1518-1527.
Aleksandrov, V.N., Tarasov, A.N., and Rozenberg, B.A., Lakokras. Mater. Ikh Primen., 1985, no. 6, pp. 35-38.
Tarasov, A.I., Shuvarin, N.A., Aleksashina, M.V., and Eselev, A.D., Lakokras. Mater. Ikh Primen., 1979, no. 6, pp. 30-32.
Kochnova, Z.A., Khrisanova, T.A., and Sorokin, M.F., Lakokras. Mater. Ikh Primen., 1989, no. 2, pp. 82-89.
Novikov, D.V. and Varlamov, A.V., Kolloidn. Zh., 1997, vol. 5?59, no. 3, pp. 355-359.
Baranov, V.G., Brestkin, Yu.V., and Frenkel, S.Ya., Dokl. Akad. Nauk SSSR, 1986, vol. 290, no. 2, pp. 369-372.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Krasovskii, A.N., Novikov, D.V., Filippov, V.N. et al. Hydrodynamic Behavior of Epoxy and Phenol-Formaldehyde Oligomers in Solution during Thermal Precondensation. Russian Journal of Applied Chemistry 76, 294–302 (2003). https://doi.org/10.1023/A:1024671116860
Issue Date:
DOI: https://doi.org/10.1023/A:1024671116860