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Determination of Herbicides of the Chlorophenoxycarboxylic Acid Type in Natural and Drinking Water by Capillary Zone Electrophoresis

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Abstract

The method of capillary electrophoresis was applied to separate and quantitatively determine herbicides belonging to the class of chlorophenoxycarboxylic acids: 2,4-dichlorophenoxyoleic, 2,4-dichlorophenoxypropionic, 2,4,5-trichlorophenoxyacetic, 2,4-dichlorophenoxyacetic, and phenoxyacetic, and the final product of their decomposition in an aqueous medium of 2,4-dichlorophenol. The influence exerted by α- and β- cyclodextrin on the selectivity of the separation system under study was analyzed. The hindering effect of humic acids on the separation and determination of phenoxycarboxylic acids by capillary electrophoresis was assessed.

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References

  1. Ding, W.H., Liu, C.H., and Yeh, S.P., J. Chromatogr., 2000, vol. 896, pp. 111-116.

    Google Scholar 

  2. Butz, S. and Snan, H.J., J. Chromatogr., 1993, vol. 643, pp. 227-232.

    Google Scholar 

  3. Balinova, A., J. Chromatogr., 1993, vol. 643, pp. 203-209.

    Google Scholar 

  4. Vandecasteele, K., Gaus, J., Debreuck, W., and Welraevens, K., Anal. Chem., 2000, vol. 72, pp. 3093-3101.

    Google Scholar 

  5. Craston, D.H. and Saeed, M., J. Chromatogr., 1998, vol. 827, pp. 1-12.

    Google Scholar 

  6. Penmetsa, K.V., Leidy, R.B., and Shea, D., J. Chromatogr., 1996, vol. 745, pp. 201-208.

    Google Scholar 

  7. Mechref, Y. and Rassi, Z.E., Anal. Chem., 1996, vol. 68, pp. 1771-1777.

    Google Scholar 

  8. Eash, D.T. and Bushway, R.J., J. Chromatogr., 2000, vol. 880, pp. 281-294.

    Google Scholar 

  9. Garrison, A.W., Schmitt, P., and Kettrup, A., J. Chromatogr., 1994, vol. 688, pp. 317-327.

    Google Scholar 

  10. Brumley, W.C. and Brownrigg, C.M., J. Chromatogr., 1994, vol. 646, pp. 377-383.

    Google Scholar 

  11. Pit'evaya voda: Gigienicheskie trebovaniya k kachestvu vody tsentralizovannykh sistem pit'evogo vodosnabzheniya. Kontrol' kachestva: Sanitarnye pravila i normy (Drinking Water: Hygienic Requirements to Quality of Water in Centralized Water Supply Systems, Quality Monitoring: Sanitarty Regulations), Moscow: Inf. Tsentr, Goskomsanepidnadzor Rossii, 1996.

  12. Normativnye dannye po predel'no dopustimym urovnyam zagryazneniya vrednymi veshchestvami ob''ektov okruzhayushchei sredy: Spravocnyi material (Standardized Data on Maximum Permissible Levels of Contamination with Harmful Substances of Environmental Objects) St. Petersburg: Petropolis, 1994.

  13. Lunev, M.M., Pestitsidy i okhrana agrofitotsenozov (Pesticides and Protection of Agrophytocenoses), Moscow: Kolos, 1992.

    Google Scholar 

  14. Host Guest Complex Chemistry Macrocycles. Synthesis, Structures, Applications, Vogtle, F. and Weber, E., Eds., Berlin: Springer, 1985.

    Google Scholar 

  15. Zolotov, Yu.A., Formanovskii, A.A., Pletnev, I.V., et al., Makrotsiklicheskie soedineniya v analiticheskoi khimii (Macrocyclic Compounds in Analytic Chemistry), Moscow: Nauka, 1993.

    Google Scholar 

  16. Orlov, D.S., Guminovye kisloty pochv i obshchaya teoriya gumifikatsii (Humic Acids and General Theory of Humification), Moscow: Mos. Gos. Univ., 1990.

    Google Scholar 

  17. Engelhardt, H., Beck, W., and Schmitt, T., Capillarelektroforese: Metoden und Moglichkeiten, Wiesbaden: Vieveg, 1994.

    Google Scholar 

  18. Handbook of Cappillary Electroforesis, Landers, J.P., Ed., Boca Raton: CRC, 1994.

    Google Scholar 

  19. Zerbinati, O., Trotta, F., and Giovannoli, C., J. Chromatogr., 2000, vol. 875, pp. 423-430.

    Google Scholar 

  20. Orlov, D.S., Gumusovye kisloty pochv (Himic Acids in Soil), Moscow: MGU, 1974.

    Google Scholar 

  21. Metody opredeleniya mikrokolichestv pestitsidov v produktakh pitaniya, kormakh i vneshnei srede (Methods for Determining Microscopic Amounts of Pesticides in Foodstuffs, Fodder, and Environment), Moscow: Kolos, 1983.

  22. Maistrenko, V.N., Khamitov, R.Z., and Budnikov, G.K., Ekologo-analiticheskii monitoring superekotoksikantov (Ecological-Analytical Monitoring of Superecotoxicants), Moscow: Khimiya, 1996

    Google Scholar 

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Komarova, N.V., Kartsova, L.A. Determination of Herbicides of the Chlorophenoxycarboxylic Acid Type in Natural and Drinking Water by Capillary Zone Electrophoresis. Russian Journal of Applied Chemistry 76, 238–243 (2003). https://doi.org/10.1023/A:1024646411409

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