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Dehydrogenation activity and structure of polyaniline supported heteropolyacid catalysts

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Abstract

Polyaniline(PAN) supported H6P2W18O62(PW) , H3PMo12O40 (PMo) and H4PMo11VO40(PMoV) catalysts were prepared and their activities for hexanol conversion were tested. IR, XRD, ICP and SEM measurements proved that the heteropolyacids (HPA) could be supported on this type of polymer. The PAN supported HPA catalysts exhibit higher redox activities and low acid-base activities for the hexanol conversion. The redox activities increase with increasing amount of the heteropolyacid. Substitution of Mo ion by V ion results in an increase of redox activities of the catalysts.

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REFERENCES

  1. T. Yamase: Chem. Rev., 98, 307 (1998).

    Article  CAS  Google Scholar 

  2. N.A. Alekar, S.B. Halligudi, R. Rajani, S. Gopinathan, C. Gopinathan: React. Kinet. Catal. Lett., 72, 169 (2001).

    Article  CAS  Google Scholar 

  3. G. Baronetti, H. Thomas, C.A. Querini: Appl. Catal. A, 217, 131 (2001).

    Article  CAS  Google Scholar 

  4. E. Coronado, J. Carlos: Chem. Rev., 98, 273 (1998).

    Article  CAS  Google Scholar 

  5. E. Dimitris, A. Katsouils: Chem. Rev., 98, 359 (1998).

    Article  Google Scholar 

  6. S.R. Mukai, I. Ogino, L. Lin, Y. Kondo, T. Masuda, K. Hashimoto: React. Kinet. Catal. Lett., 69, 253 (2000).

    Article  CAS  Google Scholar 

  7. G.I. Park, S.S. Lim, I.K. Song, W.Y. Lee: React. Kinet. Catal. Lett.,75, 157 (2002).

    Article  CAS  Google Scholar 

  8. J.F. Yu: Dissertation, Jilin University, 1996.

  9. R.D. Claude, F. Michel: Inorg. Chem., 22, 207 (1983).

    Article  Google Scholar 

  10. A. Tsigdinos, C.J. Hauada: Inorg. Chem., 7, 437 (1968).

    Article  CAS  Google Scholar 

  11. M. Hasik, W. Tarek, E. Stochmal, M. Ĺapkowski, A. Pron: J. Catal., 147, 544 (1994).

    Article  CAS  Google Scholar 

  12. J. Gong, Z.M. Su, Z.M. Dai, R.S. Wang, L.Y. Qu: Synth. Met., 46, 277 (1992).

    Article  Google Scholar 

  13. I.K. Song, M.S. Kada, G. Coulston, K. Lourtakis, M.A. Barteau: Chem. Mater., 8, 2352 (1996).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. College of Chemistry, Jilin University, Changchun, 130023, P.R. China

    Guangdong Zhou, Tiexin Cheng, Wenxing Li, Yingli Bi & Kaiji Zhen

Authors
  1. Guangdong Zhou
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  2. Tiexin Cheng
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  3. Wenxing Li
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  4. Yingli Bi
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  5. Kaiji Zhen
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Correspondence to Tiexin Cheng.

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Zhou, G., Cheng, T., Li, W. et al. Dehydrogenation activity and structure of polyaniline supported heteropolyacid catalysts. Reaction Kinetics and Catalysis Letters 79, 295–302 (2003). https://doi.org/10.1023/A:1024590203256

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