Abstract
The paper considers the application of a recently suggested mathematically correct approach for determining the rate-limiting steps, rate-determining parameters as well as the apparent activation energy for the steady occurrence of simple stepwise consecutive catalytic reactions which are linear in respect to catalytic intermediates. Under consideration are situations of both the small and large coverage of the surface with catalytic intermediates.
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Parmon, V. Rate-limiting steps, rate-determining parameters, and apparent activation energy of stepwise reactions, 2. Simple stepwise consecutive catalytic reactions linear in respect to intermediates. Reaction Kinetics and Catalysis Letters 79, 303–317 (2003). https://doi.org/10.1023/A:1024542320094
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DOI: https://doi.org/10.1023/A:1024542320094