Skip to main content
SpringerLink
Log in

Features of sulfur hexafluoride adsorption on carbon adsorbents

  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

The isotherms describing excess adsorption of SF6 and N6I6 on carbon adsorbents with different pore structures were measured at pressures of 0.001—2.4 and 0.0001—0.1 MPa, respectively, and temperatures of 298—408 E. A linear dependence of Henry"s constant on temperature in the lnK—103/O coordinates was found for all the samples. The specific surface areas of the samples determined by the BET method from the SF6 adsorption are lower than those derived from benzene adsorption. The most pronounced difference was found for the grafitized carbon black. When SF6 was adsorbed on supermicroporous carbon AC-71 and on microporous carbons PAC and CMS, a hysteresis was found, which, unlike that on mesoporous carbon adsorbents, is observed in the initial region of the equilibrium pressures.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. A. A. Opalovskii and E. U. Lobnov, Usp. Khim., 1975, 44, 193 [Russ. Chem. Rev., 1975, 44 (Engl. Transl.)].

    Google Scholar 

  2. A. A. Pribylov, Izv. Akad. Nauk, Ser. Khim., 1996, 574 [Russ. Chem. Bull., 1996, 45, 539 (Engl. Transl.)].

  3. A. A. Pribylov and G. F. Stoekli, Zh. Fiz. Khim., 1998, 72, 306 [Russ. J. Phys. Chem., 1998, 72, No. 2 (Engl. Transl.)].

    Google Scholar 

  4. V. A. Bakaev, Dokl. Akad. Nauk SSSR, 1966, 167, 369 [Dokl. Chem., 1996 (Engl. Transl.)].

    Google Scholar 

  5. G. D. Halsey, J. Chem. Phys., 1948, 16, 931.

    Google Scholar 

  6. A. A. Pribylov, I. A. Kalinnikova, S. M. Kalashnikov, and G. F. Stoekli, Izv. Akad. Nauk, Ser. Khim., 2000, 688 [Russ. Chem. Bull., Int. Ed., 2000, 49, 692].

    Google Scholar 

  7. D. W. Breck, Zeolite Molecular Sieves, Wiley-Interscience, New York-London-Sydney-Toronto, 1974.

    Google Scholar 

  8. A. A. Lopatkin, Teoreticheskie osnovy fizicheskoi adsorbtsii [Theoretical Basеs for Physical Adsorption], Izd-vo MGU, Moscow, 1983, 150 pp.

    Google Scholar 

  9. A. A. Pribylov, I. A. Kalinnikova, L. G. Shekhovtsova, and S. M. Kalashnikov, Izv. Akad. Nauk, Ser. Khim., 2000, 2026 [Russ. Chem. Bull., Int. Ed., 2000, 49, 1993].

    Google Scholar 

  10. S. J. Gregg and K. S. W. Sing, Adsorption, Surface Area and Porosity, Academic Press, London-New York, 1967, 306 pp.

    Google Scholar 

  11. A. L. McClellan and H. F. Harnsberger, J. Colloid Interface Sci., 1967, 23, 577.

    Google Scholar 

  12. R. Susmann, K. Neumann, and G. H. Findenegg, Characterization of Porous Solids, Elsevier, Amsterdam, 1988, 203.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Physical Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    A. A. Pribylov, I. A. Kalinnikova & N. I. Regent

Authors
  1. A. A. Pribylov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. I. A. Kalinnikova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. N. I. Regent
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Pribylov, A.A., Kalinnikova, I.A. & Regent, N.I. Features of sulfur hexafluoride adsorption on carbon adsorbents. Russian Chemical Bulletin 52, 882–888 (2003). https://doi.org/10.1023/A:1024492024167

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1024492024167

Search

Navigation