Abstract
The structures of products obtained by reductive debromination and CF3COOH- and KOH-induced transformations of natural chamigrane-type sesquiterpenoid (6S,10R)-10-bromo-3,11,11-trimethyl-7-methylidenespiro[5,5]undec-2-en-4-one (dactylone) isolated from the sea hare Aplysia dactylomela were analyzed. The absolute configurations of the reaction products were established by CD spectra taking into account the configuration of the starting dactylone.
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Lyakhova, E.G., Fedorov, S.N., Shubina, L.K. et al. Chemical properties of marine terpenoids. 1. Some reactions of (6S,10R)-10-bromo-3,11,11-trimethyl-7-methylidenespiro[5,5]undec-2-en-4-one, a sesquiterpenoid from the sea hare Aplysia dactylomela . Russian Chemical Bulletin 52, 1022–1026 (2003). https://doi.org/10.1023/A:1024489418232
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DOI: https://doi.org/10.1023/A:1024489418232