Abstract
Microcalorimetric measurements of excess molar enthalpies at 25°C are reported for two ternary mixtures 2,2,4-trimethylpentane + methyl tert-butyl ether + tert-amyl methyl ether and cyclohexane + methyl tert-butyl ether + tert-amyl methyl ether. Smooth representations of the results are presented and used to construct constant-enthalpy contours on Roozeboom diagrams. Comparisons of the experimental results with estimates based on the Flory theory of mixtures are also described.
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Gravelle, D., Tong, Z., Benson, G.C. et al. Excess Enthalpies of (2,2,4-Trimethylpentane or Cyclohexane) + Methyl tert-Butyl Ether + tert-Amyl Methyl Ether at 25°C. Journal of Solution Chemistry 26, 85–95 (1997). https://doi.org/10.1023/A:1024489129173
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DOI: https://doi.org/10.1023/A:1024489129173