Abstract
Crystalline specimens of homochiral and racemic glycidyl p-toluenesulfonate were studied by IR spectroscopy, differential scanning calorimetry, and X-ray diffraction analysis. The melting phase diagram of glycidyl p-toluenesulfonate was constructed. The stacking effect in the crystals of the racemic sulfonate is responsible for a more dense molecular packing, with the result that a heterochiral type of crystallization becomes more favorable.
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Bredikhin, A.A., Lazarev, S.N., Bredikhina, Z.A. et al. Crystallization of chiral compounds. 1. Spectroscopic, thermochemical, and crystallographic investigation of homochiral and racemic glycidyl p-toluenesulfonate. Russian Chemical Bulletin 52, 846–852 (2003). https://doi.org/10.1023/A:1024483822350
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DOI: https://doi.org/10.1023/A:1024483822350