Abstract
Optical and radiation-resistant crown and flint glasses exposed to gamma irradiation at room temperature are investigated. The relaxation of radiation-induced absorption in irradiated glasses is examined prior to and after short-term or long-term heat treatment at different temperatures in the range 20–150°C. It is established that an increase in the heat treatment temperature by even several tens of degrees leads to a drastic increase in the relaxation rate of radiation-induced coloration and a decrease in the time of complete bleaching of irradiated glasses by several orders of magnitude.
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REFERENCES
Bishay, A., Radiation-Induced Color Centers in Multicomponent Glasses, J. Non-Cryst. Solids, 1970, vol. 3, no. 1, pp. 54–114.
Mackey, I.H., Smith, H.L., and Halperin, A., Optical Studies in X-Irradiated High-Purity Sodium Silicate Glasses, J. Phys. Chem. Solids, 1966, vol. 27, no. 11, pp. 1759–1772.
Glebov, L.B., Dokuchaev, V.G., and Petrovskii, G.T., A Study of the Absorption Spectra for γ-Colored Silicate Glasses of High-Purity with a Variable F3+ Content, Fiz. Khim. Stekla, 1985, vol. 11, no. 1, pp. 79–96.
Arbuzov, V.I., Tolstoi, M.N., and Elerts, M.A., Absolute Characteristics of Color Centers in the Na2O · 3SiO2 Glass, Izv. Akad. Nauk SSSR, Ser. Fiz., 1986, vol. 50, no. 3, pp. 126–131.
Glebov, L.B., Dokuchaev, V.G., Petrov, M.A., and Petrovskii, G.T., Absorption Spectra of Color Centers in Alkali Silicate Glasses, Fiz. Khim. Stekla, 1990, vol. 16, no. 1, pp. 39–47.
Arbuzov, V.I., Regularities of Radiation and Postradiation Processes in Optical Glasses, Fiz. Khim. Stekla, 1996, vol. 22, no. 3, pp. 228–237 [Glass Phys. Chem. (Engl. transl.), 1996, vol. 22, no. 3, pp. 170–177].
Arbuzov, V.I., Study of Radiation Color Centers in Glasses by the Method of Post-Radiation Chronospectroscopy, Glass Sci. Technol. (Frankfurt/Main), 1998, vol. 71C, pp. 55–60.
Arbuzov, V.I. and Suchkov, F.V., Stability of Radiation-Induced Coloration of Optical Glasses, Opt. Zh., 2002, vol. 68, no. 6, pp. 85–96.
Borgman, V.A., Leko, N.A., and Kaminskaya, N.L., Decay Kinetics of Radiation-Induced Color Centers in Potassium Lead Silicate Glasses, Fiz. Khim. Stekla, 1985, vol. 11, no. 2, pp. 221–224.
Tashiro, M., Soga, N., and Sakka, S., Behavior of Cerium Ions in Glasses Exposed to X-rays, J. Ceram. Assoc. Jpn., 1960, vol. 68, no. 7, pp. 169–173.
Soga, N. and Tashiro, M., Role of Cerium Ions in Preventing the X-ray Induced Coloration of Glass, J. Ceram. Assoc. Jpn., 1962, vol. 70, no. 5, pp. 143–147.
Stroud, J.S., Colour Centers in Cerium-Containing Silicate Glasses, J. Chem. Phys., 1962, vol. 37, no. 2, pp.–836–841.
Stroud, J.S., Color-Center Kinetics in Cerium-Containing Glass, J. Chem. Phys., 1965, vol. 43, no. 7, pp. 2442–2450.
Arbuzov, V.I., Belyankina, N.B., and Solov'eva, N.D., Effect of Iron on the Formation of Color Centers in Cerium-Containing Silicate Glasses, Fiz. Khim. Stekla, 1991, vol. 17, no. 4, pp. 583–593.
Arbuzov, V.I., Photostimulated Electron Transfer between Coactivator Ions in Alkali Silicate Glasses, J. Non-Cryst. Solids, 1999, vol. 253, pp. 37–49.
Arbuzov, V.I., Britss, D.I., Rogulis, U.T., and Grabovskis, V.Ya., Thermostimulated Nonradiative Recombination of Impurity Color Centers in Sodium Silicate Glasses Coactivated with Terbium and Iron, Fiz. Khim. Stekla, 1988, vol. 14, no. 4, pp. 558–563.
Arbuzov, V.I., Tolstoi, M.N., and Elerts, M.A., Photostimulated Electron Transfer between Coactivator Ions in Sodium Silicate Glass, Fiz. Khim. Stekla, 1989, vol. 15, no. 1, pp. 103–111.
Arbuzov, V.I., Radiation-Induced Electron Transfer and the Protector Action of Cerium in Radiation-Resistant Glasses, Fiz. Khim. Stekla, 1993, vol. 19, no. 3, pp. 410–427 [Glass Phys. Chem. (Engl. transl.), 1993, vol. 19, no. 3, pp. 202–210].
Arbuzov, V.I., Vitol, I.K., Kangro, A.R., Rogulis, U.T., and Tolstoi, M.N., The Influence of Temperature on the Tunneling Luminescence of Pure and Tb(III)-Doped Na2O · 3SiO2 Glass, Fiz. Khim. Stekla, 1986, vol. 12, no. 1, pp. 75–80.
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Arbuzov, V.I., Kurochkina, M.G. Effect of Temperature on the Relaxation of Radiation-Induced Coloration in Optical Glasses. Glass Physics and Chemistry 29, 224–231 (2003). https://doi.org/10.1023/A:1024473713419
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DOI: https://doi.org/10.1023/A:1024473713419