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EPR Spectroscopy of Chalcogenide Glasses

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Abstract

Chalcogenide glasses (chalcogenide vitreous semiconductors) are systematically investigated by EPR spectroscopy. The model concepts and physicochemical principles of the EPR technique are considered as applied to the studied materials. The potentialities of the technique for studying the structure, structural defects, stoichiometry of strong interactions, and photostructural transformations are demonstrated for binary, ternary, and more complex chalcogenide vitreous systems, including halogen- and fullerene-containing systems.

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REFERENCES

  1. Blinov, L.N., Magnetic Properties of Chalcogenide Glasses, Zh. Prikl. Khim. (St. Petersburg), 1999, vol. 72, no. 7, pp. 1057–1064.

    Google Scholar 

  2. Baidakov, L.A., Blinov, L.N., and Strakhov, L.P., Magnetic Susceptibility of Lead Sulfide, Izv. Akad. Nauk SSSR, Neorg. Mater., 1967, vol. 3, no. 6, pp. 1083–1084.

    Google Scholar 

  3. Fam Zoan Han, Blinov, L.N., and Strakhov, L.P., Magnetic Susceptibility of V2O5, Fiz. Tekh. Poluprovodn. (Leningrad), 1968, vol. 2, no. 4, pp. 457–462.

    Google Scholar 

  4. Baidakov, L.A., Blinov, L.N., and Strakhov, L.P., Calculation of Polarizability of Semiconductor Glasses Transparent in the IR Spectral Range, Vestn. Leningr. Univ., 1967, no. 10, issue 2, pp. 159–160.

    Google Scholar 

  5. Blinov, L.N., Baidakov, L.A., and Strakhov, L.P., A Study of Magnetic Susceptibility of the As-Se Vitreous System, Izv. Akad. Nauk SSSR, Neorg. Mater., 1968, vol. 4, no. 1, pp. 22–27.

    Google Scholar 

  6. Baidakov, L.A., Blinov, L.N., and Strakhov, L.P., Magnetic Susceptibility of Vitreous Arsenic Chalcogenide Semiconductors, in Khimicheskaya svyaz' v kristallakh (Chemical Bonding in Crystals), Sirota, N.N., Ed., Minsk: Nauka i Tekhnika, 1969, pp. 478–484.

    Google Scholar 

  7. Novoselov, S.K., Blinov, L.N., Kazennov, B.A., Baidakov, L.A., and Strakhov, L.P., Magnetic Properties of AS2Se3 Single Crystals, Vestn. Leningr. Univ., 1970, no. 16, pp. 64–67.

  8. Blinov, L.N., On the Influence of Impurities and Local Structure of Chalcogenide Glasses on Their Magnetic Properties, in Trudy Mezhdunarodnoi konferentsii "Amorfnye poluprovodniki-80." Struktura, fizikokhimicheskie svoistva i primenenie nekristallicheskikh poluprovodnikov (Proceedings of the International Conference "Amorphous Semiconductors-80:" Structure, Physicochemical Properties, and Application of Noncrystalline Semiconductors), Chisinau: Stiintsa, 1980, pp. 193–196.

    Google Scholar 

  9. Cimpl, Z., Kosek, F., Baidakov, L.A., and Blinov, L.N., Decomposition of Magnetic Susceptibility of Diamagnets into Diamagnetic and Paramagnetic Components, Izv. Akad. Nauk SSSR, Neorg. Mater., 1981, vol. 17, no. 12, pp. 2261–2264.

    Google Scholar 

  10. Blinov, L.N., Diamagnetism and Van Vleck Paramagnetism in Semiconductors and Ionic Crystals, Fiz. Tekh. Poluprovodn. (Leningrad), 1983, vol. 17, no. 11, pp.-1975–1978.

    Google Scholar 

  11. Blinov, L.N. and Bal'makov, M.D., Interrelation between Structure of Chalcogenide Glasses and Components of Magnetic Susceptibility of Valence Electrons, Fiz. Khim. Stekla, 1983, vol. 9, no. 3, pp. 343–345.

    Google Scholar 

  12. Blinov, L.N. and Orkina, T.N., Dielectric Materials Based on Chalcogenide Vitreous Systems: Properties, Preparation Techniques, and Possibilities of Application, Zh. Prikl. Khim. (St. Petersburg), 2000, vol. 73, no. 9, pp. 1485–1495.

    Google Scholar 

  13. Baidakov, L.A., Blinov, L.N., and Gutenev, M.S., Magnetochemical Investigation of Atomic Distribution in Glasses of the P-Se-As(Ge) System, Fiz. Khim. Stekla, 1985, vol. 11, no. 6, pp. 700–702.

    Google Scholar 

  14. Ivanova, N.I., Gutenev, M.S., Blinov, L.N., and Baidakov, L.A., Magnetochemical Investigation of Glasses in the Px-S1-x System, Fiz. Khim. Stekla, 1986, vol. 12, no. 5, pp. 629–630.

    Google Scholar 

  15. Dorfman, Ya.G., Diamagnetizm i khimicheskaya svyaz' (Diamagnetism and Chemical Bonding), Moscow: Fizmatgiz, 1960.

    Google Scholar 

  16. Zakis, Yu.R., Defects and Structure Fluctuations in Vitreous Systems, Fiz. Khim. Stekla, 1989, vol. 15, no. 2, pp. 289–292.

    Google Scholar 

  17. Zakis, Yu.R., Defekty v stekloobraznom sostoyanii veshchestva (Defects in the Vitreous Materials), Riga: Zinatne, 1984.

    Google Scholar 

  18. Klyava, Ya.G., EPR spektroskopiya neuporyadochennykh tverdykh tel (EPR Spectroscopy of Disordered Solids), Riga: Zinatne, 1988.

    Google Scholar 

  19. Garif'yanov, N.S. and Tokarev, L.V., EPR Study of Crystallization of Glasses, Fiz. Tverd. Tela (Leningrad), 1964, vol. 6, no. 5, pp. 1453–1456.

    Google Scholar 

  20. Yudin, D.M., Karapetyan, G.O., and Petrovskii, G.T., EPR Investigation of Glass Structure, in Trudy V Vsesoyuznogo soveshchaniya po stekloobraznomu sostoyaniyu (Proceedings of the V All-Union Conference on the Vitreous State), Leningrad: Nauka, 1971, pp. 194–197.

    Google Scholar 

  21. Kurs lektsii po obshchei i ekologicheskoi khimii (Lecture Notes in General and Ecological Chemistry), Baidakov, L.A., Ed., St. Petersburg: St.-Peterburg. Gos. Univ., 1993.

  22. Anderson, P.W., Model for the Electronic Structure of Amorphous Semiconductors, Phys. Rev. Lett., 1975, vol. 34, no. 15, pp. 953–955.

    Google Scholar 

  23. Abdullaev, G.B., Ibragimov, N.I., Mamedov, Sh.V., Chzhuvarly, T.Ch., and Aliev, G.M., Selenium Paramagnetic Resonance, Dokl. Akad. Nauk Azerb. SSR, Ser. Fiz., 1964, vol. 20, no. 10, pp. 13–15.

    Google Scholar 

  24. Arai, K. and Namikawa, H., ESR in Ge-S Glasses, Solid State Commun., 1973, vol. 13, no. 8, pp. 1167–1170.

    Google Scholar 

  25. Gaczi, P.J., As and S Centered Paramagnetic Species in Sulphide Glasses, Philos. Mag. B, 1982, vol. 45, no. 2, pp. 241–259.

    Google Scholar 

  26. Gardner, D.M. and Fraenkel, G.K., Paramagnetic Resonance of Liquid Sulfur: Determination of Molecular Properties, J. Am. Chem. Soc., 1956, vol. 78, no. 14, pp.-3279–3288.

    Google Scholar 

  27. Amorphous Semiconductors, Brodsky, M., Ed., Heidelberg: Springer, 1979. Translated under the title Amorfnye poluprovodniki, Moscow: Mir, 1982.

  28. Radford, H.F. and Rice, F.O., Green and Purple Sulfur: Electron-Spin Resonance Studies, J. Chem. Phys., 1960, vol. 33, no. 3, pp. 774–776.

    Google Scholar 

  29. Blinov, L.N., Magnetochemical Investigation of Vitreous Semiconductor Alloys Based on Arsenic, Phosphorus, and Selenium, Abstract of Cand. Sci. Dissertation, Leningrad, 1968.

  30. Zhilinskay, E.A., Chepeleva, I.V., Lazukin, V.N., Vinogradova, G.Z., and Maysashvili, N.G., EPR of Intrinsic and Impurity Paramagnetic Centers in Ge-P-S Glass System, J. Non-Cryst. Solids, 1980, vol. 38, no. 2, pp.-317–322.

    Google Scholar 

  31. Cerny, V. and Frumar, M., ESR Study and Model of Paramagnetic Defects in Ge-S Glasses, J. Non-Cryst. Solids, 1979, vol. 33, no. 1, pp. 23–39.

    Google Scholar 

  32. Zhilinskaya, E.A., Chepeleva, I.V., Lazukin, V.N., Vinogradova, G.Z., and Maisashvili, N.G., EPR Study of Glasses in the Ge-P-S System, Fiz. Khim. Stekla, 1981, vol. 7, no. 3, pp. 288–296.

    Google Scholar 

  33. Zhilinskaya, E.A., Lazukin, V.N., Valeev, N.Kh., and Oblasov, A.K., Radiospectroscopic and X-ray Diffraction Study of Defect Formation and Structural Transformations in GexS1-x Glasses, Fiz. Khim. Stekla, 1989, vol. 15, no. 6, pp. 838–845.

    Google Scholar 

  34. Watanabe, I., Shiomi, S., and Shimizu, T., Effective Electron Correlation Energy in Amorphous Ge-S, J. Phys. Soc. Jpn., 1982, vol. 51, no. 8, pp. 2525–2531.

    Google Scholar 

  35. Bogomolova, L.D., Lazukin, V.N., and Chepeleva, I.V., Mn2+ EPR in Chalcogenide Glasses, Fiz. Tverd. Tela (Leningrad), 1964, vol. 6, no. 12, pp. 3617–3619.

    Google Scholar 

  36. Chepeleva, I.V., Shilinskay, E.A., Lazukin, V.N., Chernov, A.P., and Olkhovskii, V.I., Mn2+ EPR Study of Cu-As-Se, As-Se-I, and Cu-As-Se-I Glass Systems, Phys. Status Solidi B, 1977, vol. 82, no. 1, pp. 189–192.

    Google Scholar 

  37. Pfister, G. and Taylor, P.C., Experimental Investigation of Defect States in Amorphous Chalcogenides Glasses, J. Non-Cryst. Solids, 1980, vol. 35, no. 2, pp. 793–805.

    Google Scholar 

  38. Chepeleva, I.V., Lazukin, V.N., and Dembovsky, S.A., Mn2+ and Gd3+ EPR in 2S3 and 2S5 Glasses, Izv. Akad. Nauk SSSR, Neorg. Mater., 1968, vol. 4, no. 5, pp.661–669.

    Google Scholar 

  39. Lazukin, V.N. and Chepeleva, I.V., On the Hyperfine Structure of Mn2+ EPR Spectrum in Certain Chalcogenide Glasses, Dokl. Akad. Nauk SSSR, 1974, vol. 214, no. 4, pp. 787–790.

    Google Scholar 

  40. Chepeleva, I.V., Lazukin, V.N., and Dembovsky, S.A., Mn2+ and Gd3+ EPR in Vitreous TlAsS2, Izv. Akad. Nauk SSSR, Neorg. Mater., 1968, vol. 4, no. 11, pp. 1927–1933.

    Google Scholar 

  41. Chepeleva, I.V., Mn2+ and Gd3+ EPR in TlAsSe2 and TlAsS2 Chalcogenide Glasses in Ranges of 2 and 0.2 cm, Dokl. Akad. Nauk SSSR, 1969, vol. 185, no. 6, pp. 1266–1269.

    Google Scholar 

  42. Kumeda, M., Minato, O., Suzuki, M., and Shimizu, T., Electron Spin Resonance of Mn2+ in Amorphous Semiconductors of the System Te-As-Ge-Si, Phys. Status Solidi B, 1973, vol. 58, no. 2, pp. K155-K158.

    Google Scholar 

  43. Chepeleva, I.V. and Lazukin, V.N., Investigation into Structural Properties of Chalcogenide Glasses by EPR of Impurity Ions, in Trudy VI Mezhdunarodnoi konferentsii po amorfnym i zhidkim poluprovodnikam: Struktura i svoistva nekristallicheskikh poluprovodnikov (Proceedings of the VI International Conference on Amorphous and Liquid Semiconductors: Structure and Properties of Noncrystalline Semiconductors), Leningrad: Nauka, 1975, pp. 108–112.

    Google Scholar 

  44. Chepeleva, I.V. and Lazukin, V.N., On the EPR Line at an Isotropic g Value of 3.33 for Ions in the 6S5/2 Ground State, Fiz. Khim. Stekla, 1978, vol. 4, no. 2, pp. 242–244.

    Google Scholar 

  45. Chepeleva, I.V., On the Fine Structure of Mn2+, Fe3+, and Gd3+ EPR Spectra, Dokl. Akad. Nauk SSSR, 1972, vol. 202, no. 5, pp. 1042–1045.

    Google Scholar 

  46. Purans, J.J., Kliava, J.G., and Millere, I., Computer Simulation of Mn2+ EPR Spectra in Glasses with geff = 4.29, Phys. Status Solidi A, 1979, vol. 56, no. 1, pp. K25-K28.

    Google Scholar 

  47. Kliava, J.G. and Purans, J.J., Fine Structure Parameter Distributions for Mn2+ in Glasses, Phys. Status Solidi A, 1979, vol. 55, pp. K59-K62.

    Google Scholar 

  48. Bishop, S.G., Strom, U., and Taylor, P.C., Optically Induced Localized Paramagnetic States in Chalcogenide Glasses, Phys. Rev. Lett., 1975, vol. 34, no. 21, pp. 1346–1350.

    Google Scholar 

  49. Bishop, S.G., Strom, U., and Taylor, P.C., Optically Induced Localized Paramagnetic States in Amorphous Semiconductors, Phys. Rev. Lett., 1976, vol. 36, no. 10, pp. 543–547.

    Google Scholar 

  50. Bishop, S.G., Strom, U., and Taylor, P.C., Optically Induced Localized Paramagnetic States in Amorphous As, Solid State Commun., 1976, vol. 18, no. 5, pp. 573–576.

    Google Scholar 

  51. De Neufville, T.P., Moss, S.S., and Ovshinsky, S.R., Photostructural Transformation in Amorphous AS2Se3 Films, J. Non-Cryst. Solids, 1973, vol. 13, no. 2, pp.-191–223.

    Google Scholar 

  52. Likholit, I.L., Lyubin, V.M., Masterov, V.F., and Fedorov, V.A., Photoinduced Paramagnetic Resonance Study of Photostructural Transformations in As2S3 Films, Fiz. Tverd. Tela (Leningrad), 1984, vol. 26, no. 1, pp. 172–178.

    Google Scholar 

  53. Likholit, I.L., Lyubin, V.M., Masterov, V.F., and Fedorov, V.A., Intrinsic Paramagnetic Centers and Photostructural Transformations in 2S3 Films, Fiz. Tverd. Tela (Leningrad), 1983, vol. 25, no. 1, pp. 287–289.

    Google Scholar 

  54. Baidakov, L.A., Blinov, L.N., Likholit, I.L., and Masterov, V.F., Use of Transition Elements for Investigating Short-Range Order in Chalcogenide Glasses, Fiz. Khim. Stekla, 1983, vol. 9, no. 1, pp. 123–125.

    Google Scholar 

  55. Baidakov, L.A., Blinov, L.N., Likholit, I.L., and Masterov, V.F., State of Manganese Impurity in Semiconductor Glasses of the P-Se System, Fiz. Khim. Stekla, 1984, vol. 10, no. 6, pp. 690–694.

    Google Scholar 

  56. Baidakov, L.A. and Blinov, L.N., Tverdoe telo: amorfnoe sostoyanie veshchestva (Solids: Amorphous State of Matter), Leningrad: LPI, 1984.

    Google Scholar 

  57. Baidakov, L.A., Blinov, L.N., Borisova, Z.U., Kasatkin, B.E., Likholit, I.L., and Masterov, V.F., Intrinsic EPR Centers in Chalcogenide Semiconductor Glasses, Fiz. Tekh. Poluprovodn. (Leningrad), 1982, vol. 16, no. 4, pp. 749–751.

    Google Scholar 

  58. Baidakov, L.A., Bal'makov, M.D., and Blinov, L.N., A Fluctuation Model of Intrinsic EPR Centers in Disordered Semiconductors, in Radiospektroskopiya tverdogo tela (Radiospectroscopy of Solids), Pletnev, R.N., Ed., Sverdlovsk: Ural. Nauchn. Tsentr Akad. Nauk SSSR, 1984, pp. 17–19.

    Google Scholar 

  59. Blinov, L.N., Bal'makov, M.D., and Likholit, I.L., On the Mechanism of Formation of Intrinsic EPR Centers in Chalcogenide Glasses, Fiz. Khim. Stekla, 1984, vol. 10, no. 1, pp. 99–101.

    Google Scholar 

  60. Blinov, L.N. and Bal'makov, M.D., On the Mechanism of Formation of Photoinduced EPR Centers in Vitreous Semiconductors, Fiz. Khim. Stekla, 1985, vol. 11, no. 6, pp. 737–739.

    Google Scholar 

  61. Baidakov, L.A., Blinov, L.N., Likholit, I.L., and Masterov, V.F., NMR and EPR Spectroscopy of Chalcogenide Glasses, in Radiospektroskopiya (Materialy VII Vsesoyuznoi shkoly po magnitnomu rezonansu) [Radiospectroscopy (Proceedings of the VII All-Union Workshop on the Magnetic Resonance)], Perm: Perm. Gos. Univ., 1985, pp. 221–224.

    Google Scholar 

  62. Masterov, V.F., Likholit, I.L., Baidakov, L.A., and Blinov, L.N., Photoinduced EPR in Vitreous Semiconductors of the Phosphorus-Sulfur System, Fiz. Tekh. Poluprovodn. (Leningrad), 1985, vol. 19, no. 9, pp. 1657–1659.

    Google Scholar 

  63. Likholit, I.L., Masterov, V.F., Baidakov, L.A., and Blinov, L.N., EPR of Photoinduced Paramagnetic Centers in Chalcogenide Vitreous Semiconductors, Fiz. Tverd. Tela (Leningrad), 1987, vol. 29, no. 3, pp. 881–884.

    Google Scholar 

  64. Bagraev, N.T., Blinov, L.N., and Romanov, V.V., Self-Compensation of Metastable Centers in Chalcogenide Semiconductor Glasses, Fiz. Tverd. Tela (St. Petersburg), 2002, vol. 44, no. 5, pp. 785–791.

    Google Scholar 

  65. Bagraev, N.T., Blinov, L.N., and Romanov, V.V., Magnetic Properties for Metastable Negative-U Defects in Amorphous Semiconductors, Solid State Commun., 2002, vol. 121, pp. 417–421.

    Google Scholar 

  66. Myuller, R.L., Chemistry of Solids and the Vitreous State, in Khimiya tverdogo tela (Chemistry of Solids), Borisova, Z.U., Ed., Leningrad: Leningrad. Gos. Univ., 1965, pp. 9–63.

    Google Scholar 

  67. Borisova, Z.U., Khal'kogenidnye poluprovodnikovye stekla (Chalcogenide Semiconductor Glasses), Leningrad: Leningrad. Gos. Univ., 1983.

    Google Scholar 

  68. Frumar, M., Chemie pevnych latek, Pardulice, 1992.

  69. Feltz, A., Amorphe und glasartige anorganische Festkörper (Amorphous and Vitreous Inorganic Solids), Berlin: Akademie, 1983. Translated under the title Amorfnye i stekloobraznye neorganicheskie tverdye tela, Moscow: Mir, 1986.

    Google Scholar 

  70. Orkina, T.N. and Blinov, L.N., Fluorochalcogenide Glasses, Fiz. Khim. Stekla, 2000, vol. 26, no. 3, pp.–393–402 [Glass Phys. Chem. (Engl. transl.), 2000, vol. 26, no. 3. pp. 274–279].

    Google Scholar 

  71. Bal'makov, M.D., Stekloobraznoe sostoyanie veshchestva (The Vitreous State of Matter), St. Petersburg: St.-Peterburg. Gos. Univ., 1996.

    Google Scholar 

  72. Blinov, L.N., EPR Spectroscopy of Chalcogenide Vitreous Semiconductors, Nauch.-Tekh. Vedom. St. Petersburg Gos. Univ., 1999, no. 3(17), pp. 124–132.

    Google Scholar 

  73. Tver'yanovich, Yu.S. and Gutenev, M.S., Magnetokhimiya stekloobraznykh poluprovodnikov (Magnetochemistry of Vitreous Semiconductors), St. Petersburg: St.-Peterburg. Gos. Univ., 1997.

    Google Scholar 

  74. Mazurin, O.V., Steklovanie (Glass Transition), Leningrad: Nauka, 1986.

    Google Scholar 

  75. Kokorina, V.F., Myuller and Tarasov Polymeric Concepts and Classical Aspects of Glass Formation, in Novye idei v fizike stekla (New Ideas in Glass Physics), Moscow: MKhTI, 1987, vol. 1, pp. 3–10.

    Google Scholar 

  76. Nemilov, S.V., Thermodynamic Functions of Nonequilibrium Disordered Systems at Absolute Zero and the Nature of the Vitreous State, Fiz. Khim. Stekla, 1982, vol. 8, no. 1, pp. 11–24.

    Google Scholar 

  77. Rawson, H., Inorganic Glass-Forming Systems, New York: Academic, 1967. Translated under the title Neorganicheskie stekloobrazuyushchie sistemy, Moscow: Mir, 1970.

    Google Scholar 

  78. Mott, N. and Davis, E., Electronic Processes in Non-Crystalline Materials, Oxford: Oxford Univ. Press, 1979. Translated under the title Elektronnye protsessy v nekristallicheskikh veshchestvakh, Moscow: Mir, 1982.

    Google Scholar 

  79. Adler, D., Devices Based on Amorphous Semiconductors, Usp. Fiz. Nauk, 1978, vol. 125, no. 4, pp. 707–730.

    Google Scholar 

  80. Abragam, A. and Bleaney, B., Electron Paramagnetic Resonance of Transition Ions, Oxford: Clarendon, 1970. Translated under the title Elektronnyi paramagnitnyi rezonans perekhodnykh ionov, Moscow: Mir, 1972, vol. 1.

    Google Scholar 

  81. Pakc, G., Paramagnetic Resonance, New York: Academic, 1962. Translated under the title Paramagnitnyi rezonans, Moscow: Inostrannaya Literatura, 1965.

    Google Scholar 

  82. Poole, Ch., Electron Spin Resonance: A Comprehensive Treatise on Experimental Techniques, New York: Wiley, 1967. Translated under the title Tekhnika EPR spektroskopii, Moscow: Mir, 1970.

    Google Scholar 

  83. Low, W., Paramagnetic Resonance in Solids, Oxford: Clarendon, 1959. Translated under the title Paramagnitnyi rezonans v tverdykh telakh, Moscow: Inostrannaya Literatura, 1962.

    Google Scholar 

  84. Swalen, J.D. and Gladney, H.M., Computer Analysis of Electron Paramagnetic Resonance Spectra, IBM Res. Dev., 1964, vol. 8, no. 5, pp. 515–526.

    Google Scholar 

  85. Vinokurov, V.M., Zaripov, M.M., and Stepanov, V.G., Mn2+ EPR in Diopside Crystals, Fiz. Tverd. Tela (Leningrad), 1964, vol. 6, no. 4, pp. 1130–1137.

    Google Scholar 

  86. Taylor, P.S., Baucher, J.F., and Kriz, H.M., Magnetic Resonance Spectra in Polycrystalline Solids, Chem. Rev., 1975, vol. 75, no. 2, pp. 203–240.

    Google Scholar 

  87. Bloch, F., Nuclear Induction, Phys. Rev., 1946, vol. 70, no. 7, pp. 460–474.

    Google Scholar 

  88. Hugles, D.G. and Rowland, T.J., Theoretical Line Shapes Associated with Anisotropic Knights: Shifts and Quadrupole Interactions in Polycrystalline Samples, Can. J. Phys., 1964, vol. 42, no. 1, pp. 2009–2013.

    Google Scholar 

  89. Meisel, W., Inhomogeneities in Solids Measured by Approximate Defording of Mössbauer Spectra, Phys. Status Solidi B, 1971, vol. 43, no. 2, pp. K129-K131.

    Google Scholar 

  90. Elste, G., Die Entzerrung von Spektrallinier unter Verwendung von Voighfunktionen, Z. Astrophys., 1953, vol. 33, no. 1, pp. 33–73.

    Google Scholar 

  91. Sands, R.H., Paramagnetic Resonance Absorption in Glass, Phys. Rev., 1955, vol. 99, no. 4, pp. 1222–1226.

    Google Scholar 

  92. Ibers, J.A. and Swalen, J.D., Paramagnetic Resonance Line Shapes and Magnetic Parameters of Polycrystalline Substances, Phys. Rev., 1962, vol. 127, no. 6, pp.-1914–1917.

    Google Scholar 

  93. Abragam, A.A., The Principles of Nuclear Magnetism, Oxford: Clarendon, 1961. Translated under the title Yadernyi magnetizm, Moscow: Inostrannaya Literatura, 1963.

    Google Scholar 

  94. Gersmann, H.R. and Swalen, J.D., Electron Paramagnetic Resonance Spectra of Copper Complex, J. Chem. Phys., 1962, vol. 36, no. 12, pp. 3221–3233.

    Google Scholar 

  95. Strauss, G.H., Nuclear Magnetic Resonance Determination of Some Microscopic Parameters of LiAl5O8, J. Chem. Phys., 1964, vol. 40, no. 7, pp. 1988–1991.

    Google Scholar 

  96. Searl, J.W., Smith, R.C., and Wayrd, S.J., Electron Spin Resonance Absorption for Polycrystalline Substances, Proc. Phys. Soc. London, 1961, vol. 78, no. 50, pp.-1174–1176.

    Google Scholar 

  97. Zhidomirov, G.M., Lebedev, Ya.S., and Dobryakov, S.N., Interpretatsiya slozhnykh spektrov EPR (Interpretation of Complex EPR Spectra), Moscow, 1975.

  98. Isomoto, A., Watari, H., and Kotani, M., Dependence of EPR Transition Probability on Magnetic Fields, J. Phys. Soc. Jpn., 1970, vol. 29, no. 6, pp. 1571–1577.

    Google Scholar 

  99. Baidakov, L.A., Magnetochemical Investigation of Vitreous Semiconductors, Abstract of Doctoral Dissertation, Leningrad, 1975.

  100. Chepeleva, I.V., Zhilinskaya, E.A., and Lazukin, V.N., Impurity and Intrinsic Paramagnetic Centers in Chalcogenide Glasses, in Struktura, fiziko-khimicheskie svoistva i primenenie nekristallicheskikh poluprovodnikov (Structure, Physicochemical Properties, and Application of Noncrystalline Semiconductors), Chisinau: Stiintsa, 1980, pp. 197–200.

    Google Scholar 

  101. Sampath, P.I., EPR in Selenium, J. Chem. Phys., 1966, vol. 45, no. 10, pp. 3519–3525.

    Google Scholar 

  102. Masterov, V.F., EPR Study of Selenium, Abstract of Cand. Sci. Dissertation, Leningrad, 1970.

  103. Bishop, S.G., Strom, U., and Taylor, P.C., Optically Induced Metastable Paramagnetic States in Amorphous Semiconductors, Phys. Rev., 1977, vol. 15, no. 4, pp.-2278–2294.

    Google Scholar 

  104. Shanabrook, B.V., Bishop, S.G., and Taylor, P.S., Photoluminescence and EPR Studies of Localized States in Amorphous Phosphorus, J. Phys. (Paris), 1981, vol. 42, no. 10, pp. C4865-C4868.

    Google Scholar 

  105. Taylor, P.S., Friebcle, E.J., and Bishop, S.G., Thermally Generated Paramagnetism in Amorphous Arsenic, Solid State Commun., 1978, vol. 28, no. 1, pp. 247–250.

    Google Scholar 

  106. Zhilinskaya, E.A., Chepeleva, I.V., Lazukin, V.N., Vinogradova, G.Z., and Maisashvili, N.G., Paramagnetic Centers in Semiconductor Glasses of the Ge-P-S System, Fiz. Khim. Stekla, 1983, vol. 9, no. 3, pp. 267–274.

    Google Scholar 

  107. Buttet, J., Etude des centres paramagnetiques du soufre condence a basse temperature: Fonctions d' onde d' une chaine de soufre, Helv. Phys. Acta, 1969, vol. 42, no. 1, pp. 63–101.

    Google Scholar 

  108. Gutenev, M.S., Dielcometric Investigation of Glasses in the (2S3)1-x(P2S5)x System, Fiz. Khim. Stekla, 1987, vol. 13, no. 7, pp. 308–310.

    Google Scholar 

  109. Wibbedman, G. and Brockner, W., Under Suchum gen zum Strukturanfban von AS2S2S7 und (AS2P2S8)n, Z. Naturforsch., 1981, vol. 36, no. 8, pp. 836–841.

    Google Scholar 

  110. Vinogradova, G.Z., Stekloobrazovanie i fazovye ravnovesiya v khal'kogenidnykh sistemakh (Glass Formation and Phase Equilibria in Chalcogenide Systems), Moscow: Nauka, 1984.

    Google Scholar 

  111. Monteil, Y. and Vincent, H., A Study of the Amorphous Domain in the System P-Se-S: Synthesis and Characterisation of the Amorphous Compound P4Se10, Z. Anorg. Allg. Chem., 1977, vol. 428, pp. 259–268.

    Google Scholar 

  112. Vincent, H., Diagramme de phases phosphore-soufre, Bull. Soc. Chim. Fr., 1972, no. 12, pp. 4517–4521.

  113. Kudryavtsev, A.N., Baidakov, L.A., and Blinov, L.N., NMR and EPR Study of Electronic Structure of Glasses Containing Thallium, in Amorfnye poluprovodniki-82 (Amorphous Semiconductors-82), Bucharest, vol. R, 1982, pp. 169–171.

    Google Scholar 

  114. Tanaka, K. and Odajima, A., Configuration-Coordinate Model for Photodarkening in Amorphous 2S3, J. Non-Cryst. Solids, 1981, vol. 46, no. 3, pp. 259–268.

    Google Scholar 

  115. Blinov, L.N. and Baidakov, L.A., Application of Proton Resonance to Investigation of Magnetic Properties of Amorphous Semiconductors, in Amorfnye poluprovodniki-78 (Amorphous Semiconductors-78), Pardubice, 1978, vol. 1, pp. 325–327.

    Google Scholar 

  116. Blinov, L.N., Borisova, Z.U., and Baidakov, L.A., Electrical Conductivity and Magnetic Susceptibility of Arsenic Selenides Enriched in Selenium, Vestn. Leningr. Univ., Ser. 4: Fiz., Khim., 1970, no. 10, issue 2, pp.–116–122.

    Google Scholar 

  117. Blinov, L.N., Baidakov, L.A., and Korneev, V.R., NMR Study of Vitreous Chalcogenides, in Sovremennye metody EPR i YaMR v khimii tverdogo tela (EPR and NMR Modern Techniques in Chemistry of Solids), Chernogolovka, 1982, pp. 47–48.

  118. Blinov, L.N., Diamagnetism and Chemical Bonding in Chalcogenide Glasses, in Elektronnyi paramagnitnyi rezonans v tverdofaznykh soedineniyakh (Electron Paramagnetic Resonance in Solid-Phase Materials), Sverdlovsk: Ural. Otd. Akad. Nauk SSSR, 1989, pp.–46–49.

    Google Scholar 

  119. Rao, K.J. and Rao, B.G., Electron Spin Resonance of Transition Metal Ions in Glasses, Proc. Indian Acad. Sci., Chem. Sci., 1985, vol. 95, no. 1, pp. 169–188.

    Google Scholar 

  120. Baidakov, L.A., Blinov, L.N., Likholit, I.L., and Masterov, V.F., Spin Label Technique for Investigating the Short-Range Order and Structural Transformations in Glasses, Tezisy dokladov VII Vsesoyuznogo simpoziuma po spektroskopii kristallov, aktivirovannykh ionami redkozemel'nykh i perekhodnykh metallov (Abstracts of Papers of VII All-Union Symposium on Spectroscopy of Crystals Activated by Rare-Earth and Transition Metal Ions), Leningrad, 1982, pp. 270–271.

  121. Tver'yanovich, Yu.S., Popova, T.K., Kvantov, M.A., and Blinov, L.N., Magnetic Properties of Sb19Ge22Se56 Glass Containing Cobalt Impurity, Fiz. Khim. Stekla, 1986, vol. 12, no. 6, pp. 739–741.

    Google Scholar 

  122. Cerny, V., Experimental and Theoretical Reasons for Inclusion of Four-Order Terms into Spin Hamiltonian of Glasses Doped by d5 Impurities with 6A1 Ground States, Philos. Mag. B, 1992, vol. 65, no. 3, pp. 401–420.

    Google Scholar 

  123. Petrova, B., Frumar, M., Cernoskova, E., Pavlik, I., and Blinov, L.N., ESP and Optical Spectra of Co2+ Doped CdX2-PbX2-KI Glasses (X = Cl, Br), Mater. Sci. Forum, 1991, vol. 67/68, pp. 537–542.

    Google Scholar 

  124. Klingen, W., Ott, R, and Hahn, H., Uber die Darstellung von Eigenschaften von Hexathio-und Hexaselenohypodiphosphaten, Z. Anorg. Allg. Chem., 1973, vol. 396, no. 3, pp. 271–278.

    Google Scholar 

  125. Clement, R., Girerd, J.J., and Morgenstern-Badaran, I., Dramatic Modification of the Magnetic Properties of Lamellar MnPSe3 upon Intercalation, Inorg. Chem., 1980, vol. 19, no. 9, pp. 2852–2854.

    Google Scholar 

  126. Blinov, L.N., Likholit, I.L., Ananichev, V.A., Orkina, T.N., Baidakov, L.A., Lizorkin, V.I., and Pocheptsova, N.S., Preparation and Properties of Disordered Selenium Carbon Matrices Containing Fullerene, Pis'ma Zh. Tekh. Fiz., 1993, vol. 19, no. 12, pp. 47–50.

    Google Scholar 

  127. Baidakov, L.A., Blinov, L.N., Kuznetsova, L.A., and Pocheptsova, N.S., On the Relation of Superconductivity to the Nature of Chemical Interaction between Components of a Material, Pis'ma Zh. Tekh. Fiz., 1995, vol. 21, no. 6, pp. 74–78.

    Google Scholar 

  128. Bal'makov, M.D., Blinov, L.N., and Baidakov, L.A., Vitreous Selenium Containing Fullerenes, Fiz. Khim. Stekla, 1995, vol. 21, no. 4, pp. 321–329 [Glass Phys. Chem. (Engl. transl.), 1995, vol. 21, no. 4. pp. 235–241].

    Google Scholar 

  129. Blinov, L.N., Bal'makov, M.D., and Pocheptsova, N.S., On the Superconductivity of Disordered Systems with a Decreased Configurational Entropy, Pis'ma Zh. Tekh. Fiz., 1996, vol. 22, no. 21, pp. 69–73.

    Google Scholar 

  130. Blinov, L.N., Noskova, N.A., Orkina, T.N., Karataev, V.A., and Pocheptsova, N.S., A Study of Chalcogenide Vitreous Compounds Containing Fullerene, Pis'ma Zh. Tekh. Fiz., 1996, vol. 22, no. 9, pp. 47–50.

    Google Scholar 

  131. Blinov, L.N. and Kuznetsova, L.A., Fullerene-Doped Chalcogenide Glasses, J. Mater. Sci. Lett., 2002, vol. 21, no. 2, pp. 165–167.

    Google Scholar 

  132. Wertz, I. and Bolton, J., Electron Spin Resonance, New York: McGraw-Hill, 1972. Translated under the title Teoriya i prakticheskie prilozheniya metoda EPR, Moscow: Mir, 1975.

    Google Scholar 

  133. Mokhammad Arif, Tolochko, O.V., and Blinov L.N., Glass Formation and Properties of Alloys in the (Sb2A3)1-x (CuI) x System (A = S and Se), Fiz. Khim. Stekla, 1998, vol. 24, no. 4, pp. 499–501 [Glass Phys. Chem. (Engl. transl.), 1998, vol. 24, no. 4, pp. 348–349].

    Google Scholar 

  134. Blinov, L.N., Gutenev, M.S., Nenashev, B.G., and Popov, S.P., Vitreous Ag3AsS3 and Its Properties, Fiz. Khim. Stekla, 1989, vol. 15, no. 1, pp. 144–146.

    Google Scholar 

  135. Ananichev, V.A. and Mokhammad Arif, Method of Preparing High-Purity Tellurium, RF Patent 2085482, Byull. Izobret., 1997, no. 21.

  136. Ananichev, V.A., Voronova, A.E., and Blinov, L.N., Thermal Expansion of Arsenic, Zh. Prikl. Khim. (St. Petersburg), 2002, vol. 75, no. 10, pp. 1743–1744.

    Google Scholar 

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Blinov, L.N. EPR Spectroscopy of Chalcogenide Glasses. Glass Physics and Chemistry 29, 203–223 (2003). https://doi.org/10.1023/A:1024432629349

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