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New approach to stereochemical structure determination of bis-selenium-subsituted alkenes

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Abstract

A new approach to determination of the stereochemical structure of bis-selenium-substituted alkenes using experimental 77Se NMR studies and B3LYP/6-311G(d) quantum-chemical calculations is developed. Joint analysis of experimental and calculated data allows assignment of signals in the 77Se NMR spectrum. The method was evaluated taking the model compounds (PhSe)HC=C(SePh)R (R = COOMe, CH2NMe2, CH2OH, Ph) as examples.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    V. P. Ananikov

  2. Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, 119992, Moscow, Russian Federation

    I. P. Beletskaya

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  1. V. P. Ananikov
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  2. I. P. Beletskaya
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Ananikov, V.P., Beletskaya, I.P. New approach to stereochemical structure determination of bis-selenium-subsituted alkenes. Russian Chemical Bulletin 52, 811–816 (2003). https://doi.org/10.1023/A:1024423603695

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