Skip to main content
SpringerLink
Log in

Synthesis and structural characterization of a (N,N′-bis[2(S)-pyrrolidylmethyl]-propane-1,3-diamine) nickel (II) complex

  • Published:
Journal of Chemical Crystallography Aims and scope Submit manuscript

Abstract

The nickel(II) complex [Ni(C4H3NCH=N–(CH2)3–N=CHC4H3N)], (1) containing the symmetrical N4 tetradentate Schiff base ligand, which is the 2:1 condensation product of pyrrole-2-carboxaldehyde and 1,3-diaminopropane respectively, was prepared. Structural investigation shows that it is monomeric, having space group P21/c, a = 7.989(7), b = 17.406(14), c = 9.193(5) Å, α = 90, β = 100.39(6), γ = 90○, and Z = 4. The coordination geometry around the nickel atom is slightly distorted square planar and the conformation of the six-membered ring containing the metal,azomethine nitrogens and three carbon atoms of the connecting 1,3-diaminopropane is a symmetric boat.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Sessler, J.L.; Sibert, J.W.; Lynch, V. Inorg. Chem. 1990, 29, 4143.

    Google Scholar 

  2. Brudenell, S.J.; Spiccia, L.; Tiekink, E.R.T. Inorg. Chem. 1996, 35, 1974.

    Google Scholar 

  3. Whitmore, B.C.; Eisenberg, R. Inorg. Chem. 1983, 22, 1.

    Google Scholar 

  4. Wieghardt, K.; Tolksdorf, I.; Herrmann, W. Inorg. Chem. 1985, 24, 1230.

    Google Scholar 

  5. Lee, D.H.; Murthy, N.N.; Karlin, K.D. Inorg. Chem. 1996, 35, 804.

    Google Scholar 

  6. Zacharias, P.S.; Ramachandraiah, A. Polyhedron 1985, 4, 1013.

    Google Scholar 

  7. Villa, J.F.; Hatfield, W.E. J. Am. Chem. Soc. 1971, 93, 4081.

    Google Scholar 

  8. Sessler, J.L.; Sibert, J.W.; Lynch, V.; Markert, J.T.; Wooten, C.L. Inorg. Chem. 1993, 32, 621.

    Google Scholar 

  9. Inman, G.W.; Hatfield, W.E., Jr. Inorg. Chem. 1972, 11, 3085.

    Google Scholar 

  10. Lindoy, L.F. The Chemistry of Macrocyclic Ligands; Cambridge University Press: Cambridge, 1989.

    Google Scholar 

  11. Vigato, P.A.; Tamburim, S.; Fenton, D.E. Coord. Chem. Rev. 1990, 106, 25.

    Google Scholar 

  12. Gamovskii, A.D.; Nivorozhkin, A.L.; Minkin, V.I. Coord. Chem. Rev. 1993, 126, 1.

    Google Scholar 

  13. Zanello, P.; Tamburim, S.; Vigato, P.A.; Mazzocchin, G.A. Coord. Chem. Rev. 1987, 77, 165.

    Google Scholar 

  14. Carlisle, W.D.; Fenton, D.E.; Roberts, P.B.; Casellato, U.; Vigato, P.A.; Graziani, R. Trans. Met. Chem. 1986, 11, 292.

    Google Scholar 

  15. Ikawa, Y.; Nagata, T.; Maruyama, K. Chem. Lett. 1993, 1049.

  16. Aono, T.; Wada, H.; Aratake, Y.; Matsumoto, N.; Okawa, H.; Matstuda, Y. J. Chem. Soc., Dalton Trans. 1996, 25.

  17. Timken, M.D.; Marrit, W.A.; Hendrickson, D.N.; Gagne, R.R.; Sinn, E. Inorg. Chem. 1985, 24, 4202.

    Google Scholar 

  18. Martel, A.E. Oxygen Complexes and Oxygen Activation by Transition Metal; Plenum: New York, 1998; p.87.

    Google Scholar 

  19. Casella, L.; Gubotti, M.; Pintar, K.; Messoori, A.; Rockenbauer, L.A.; Gyor, M. Inorg. Chem. 1987, 26, 1031.

    Google Scholar 

  20. Tabchek, M.; El-Achbar, A.; Pappalardo, L.; Roumestant, M.L.; Viallefont, P. Tetrahedron 1991, 47, 4611.

    Google Scholar 

  21. Berkessel, A.; Bolte, M.; Nemann, T.; Seidel, L. Chem. Ber. 1996, 129, 1183.

    Google Scholar 

  22. Hernández-Molina, R.; Mederos, A.; Gili, P.; Domínguez, S.; Núñez, P.; Germain, G.; Debaerdemaeker, T. Inorg. Chim. Acta 1997, 256, 319.

    Google Scholar 

  23. Brewer, G.; Kamaras, P.; May, L.; Prytkov, S.; Rapta, M. Inorg. Chim. Acta 1998, 279, 111.

    Google Scholar 

  24. Szlyk, E.; Wojtczak, A.; Larsen, E.; Surdykowski, A.; Neumann, J. Inorg. Chim. Acta 1999, 293, 239.

    Google Scholar 

  25. Mondal, N.; Saha, M.K.; Bag, B.; Mitra, S.; Rosair, G.; El Fallah, M.S. Polyhedron 2001, 20, 579.

    Google Scholar 

  26. Mondal, N.; Mitra, S.; Rosair, G. Polyhedron 2001, 20, 2473.

    Google Scholar 

  27. Mondal, N.; Mitra, S.; Gramlich, V.; Ghodsi, S.O.; Malik, K.M.A. Polyhedron 2001, 20, 135.

    Google Scholar 

  28. Choudhury, C.R.; Dey, S.K.; Mitra, S.; Ghodsi, S.O.; Malik, K.M.A. J. Chem. Crys. in press.

  29. Sheldrick, G.M. SHELXTL-PLUS: Program for the Solution of Crystal Structures; University of Göttingen: Germany, 1990.

    Google Scholar 

  30. Sheldrick, G.M. SHELXL-96, Program for Crystal Structure Refinement; University of Göttingen: Germany, 1996.

    Google Scholar 

  31. Diaz, A.; García, I.; Cao, R.; Beraldo, H.; Salberg, M.M.; West, D.X.; González, L.; Ochoa, E. Polyhedron 1997, 16, 3549.

    Google Scholar 

  32. Lever, A.B.P. Inorganic Electronic Spectroscopy, 2nd ed.; Elsvier: Amsterdam, 1984; p.535.

    Google Scholar 

  33. Kim, D.-Y.; Lee, D.-J.; Heo, N.H.; Jung, M.-J.; Lee, B.-W.; Oh, C.-E.; Doh, M.-K. Inorg. Chim. Acta. 1998, 267, 127.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Jadavpur University, Calcutta, 700032, India

    Amitabha Datta, Nirmal Kumar Karan, Samiran Mitra & Volker Gramlich

Authors
  1. Amitabha Datta
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Nirmal Kumar Karan
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Samiran Mitra
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Volker Gramlich
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Samiran Mitra.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Datta, A., Karan, N.K., Mitra, S. et al. Synthesis and structural characterization of a (N,N′-bis[2(S)-pyrrolidylmethyl]-propane-1,3-diamine) nickel (II) complex. Journal of Chemical Crystallography 33, 579–583 (2003). https://doi.org/10.1023/A:1024299005045

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1024299005045

Search

Navigation