Skip to main content
SpringerLink
Log in

Sorption–Chromatographic Determination of Aniline, 4-Chloroaniline, and 2,5-Dichloroaniline in Air

  • Published:
Journal of Analytical Chemistry Aims and scope Submit manuscript

Abstract

Conditions were found for the chemisorption preconcentration of aniline, 4-chloroaniline, and 2,5-dichloroaniline from air using tubes packed with silica gel with immobilized 4-chloro-5,7-dinitrobenzofurazan and for the subsequent HPLC determination with diode-array detection. The maximum analyte recoveries (98, 90, and 75% for aniline, 4-chloroaniline, and 2,5-dichloroaniline, respectively) were achieved at a 2-cm thickness of the adsorbent layer (silica gel with a grain size of 0.1–0.3 mm impregnated with 3 wt % 4-chloro-5,7-dinitrobenzofurazan), an aspiration rate of 0.6–0.8 L/min, and an aspirated air volume of 10 L. Taking into account a tenfold preconcentration of analytes after the desorption, the detection limit for aniline is equal to 0.0007 mg/m3.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. Nikolaev, Yu.T. and Yakubson, A.M., Anilin (Aniline), Moscow: Khimiya, 1984.

    Google Scholar 

  2. Ambient Measurement Methods and Properties of the 189 Clean Air Hazardous Air Pollutants, US EPA, 1994, 600/R-94/098.

  3. Ward, E.M., Sabbioni, G., DeBord, D.G., Teass, A.W., Brown, K.K., Talaska, G.G., Roberts, D.R., Ruder, A.M., and Streiher, R.P.,J. Natl. Cancer Inst., 1996, vol. 88, no. 15, p. 1046.

    Google Scholar 

  4. Gadaskina, I.D. and Firsov, V.A., Prevrashchenie i raspredelenie promyshlennykh organicheskikh yadov v organizme (Metabolism and Distribution of Industrial Organic Poisons in Human Body), Moscow: Meditsina, 1971.

    Google Scholar 

  5. Bespamyatnov, G.P. and Krotov, Yu.A., PDK khimicheskikh veshchestv v okruzhayushchei srede: spravochnik (Maximum Allowable Concentrations of Chemical Substances in the Environment: Reference Book), Leningrad: Khimiya, 1985.

    Google Scholar 

  6. Murav'ev, S.M., Bukovskii, M.I., Prokhorova, E.K., et al., Rukovodstvo po kontrolyu vrednykh veshchestv v vozdukhe rabochei zony (A Guide on Control of Hazardous Substances in Working-Zone Air), Moscow: Khimiya, 1991.

    Google Scholar 

  7. Skarping, G., Renman, L., and Dalene, M., J. Chromatogr., 1983, vol. 270, p. 207.

    Google Scholar 

  8. Gao, Ch.X., Krull, I.S., and Trainor, T.M., J. Chromatogr., 1989, vol. 463, p. 192.

    Google Scholar 

  9. Watanabe, Y. and Imai, K., Anal. Chem., 1983, vol. 55, p. 1786.

    Google Scholar 

  10. Elskamp, C.J. and Schultz, G.R., Am. Ind. Hyg. Assoc. J., 1986, vol. 47, no. 1, p. 41.

    Google Scholar 

  11. Seeber, G., Buchmeiser, M.R., Bonn, G.K., and Bertsch, Th., J. Chromatogr., 1998, vol. 809, p. 121.

    Google Scholar 

  12. Method 73, OSHA Analytical Methods Manual, parts I and II, Salt Lake City: US OSHA, 1990, 2nd ed.

  13. Method CLP-2, US EPA Contract Laboratory Program Statement of Work for Analysis of Ambient Air, Rev. IAIR01.2, US EPA, Research Triangle Park, 1993.

  14. Compendium Method TO-17: Determination of Volatile Organic Compounds in Ambient Air Using Active Sampling onto Sorbent Tubes, Compendium of Methods for the Determination of Toxic Organic Compounds in Ambient Air, Cincinnati: US EPA, 1997.

    Google Scholar 

  15. Newman, A.R., Anal. Chem., 1991, vol. 63, no. 4, p. 237.

    Google Scholar 

  16. Evgen'ev, M.I., Garmonov, S.Yu., Evgen'eva, I.I., and Budnikov, G.K., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 1995, vol. 38, nos. 1–2, p. 66.

    Google Scholar 

  17. Evgen'ev, M.I., Garmonov, S.Yu., and Medvedev, V.V., Zavod. Lab., 1996, vol. 62, no. 3, p. 8.

    Google Scholar 

  18. Evgen'ev, M.I., Garmonov, S.Yu., Evgen'eva, I.I., Goryunova, S.M., Nikolaeva, N.G., and Levinson, F.S., Zh. Anal. Khim., 1998, vol. 53, no. 2, p. 175.

    Google Scholar 

  19. Evgen'ev, M.I., Evgen'eva, I.I., and Levinson, F.S., J. Planar Chromatogr., 2000, vol. 13, no. 3, p. 199.

    Google Scholar 

  20. Beyermann, K., Organic Trace Analysis, Chichester: Ellis Horwood, 1984. Translated under the title Opredelenie sledovykh kolichestv organicheskikh veshchestv, Moscow: Mir, 1987, p. 163.

    Google Scholar 

  21. Evgen'ev, M.I. and Evgen'eva, I.I., Vestn. TO Ross. Ekol. Akad., 2001, nos. 3–4, p. 65.

    Google Scholar 

  22. Tsentovskii, V.M., Levinson, F.S., Evgen'ev, M.I., Sharnin, G.P., Akimova, S.A., and Petushkova, N.I., Zh. Obshch. Khim., 1988, vol. 58, no. 5, p. 1080.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Kazan State Technological University, ul. Karla Marksa 68, 420015, Kazan, Tatarstan, Russia

    M. I. Evgen'ev, I. I. Evgen'eva, S. Yu. Garmonov & R. N. Ismailova

Authors
  1. M. I. Evgen'ev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. I. I. Evgen'eva
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. Yu. Garmonov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. R. N. Ismailova
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Evgen'ev, M.I., Evgen'eva, I.I., Garmonov, S.Y. et al. Sorption–Chromatographic Determination of Aniline, 4-Chloroaniline, and 2,5-Dichloroaniline in Air. Journal of Analytical Chemistry 58, 542–547 (2003). https://doi.org/10.1023/A:1024160001704

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1024160001704

Keywords

Search

Navigation