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Crystal Structure of (Ti,Mo)12P7and Refined Phase Equilibria in the Ti–Mo–P System

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Abstract

A new ternary compound of composition Ti3.8Mo8.2P7.0 was identified, and its structure was determined by single-crystal x-ray diffraction: sp. gr. P 6¯, a= 1.67821(6) nm, c= 0.33196(2) nm; R F = 0.073 and R w = 0.078 for 1359 independent reflections with F hkl > 4σ(F hkl ). The phase equilibria in the Ti–Mo–P system were refined in the region 0–25 mol % Ti and 33–40 mol % P.

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  1. Franko State University, ul. Kirila i Mefodiya 6, Lviv, 79005, Ukraine

    Ya. F. Lomnytska, S. V. Oryshchyn, V. S. Babizhetskii & Yu. B. Kuz'ma

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  1. Ya. F. Lomnytska
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  2. S. V. Oryshchyn
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  3. V. S. Babizhetskii
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  4. Yu. B. Kuz'ma
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Lomnytska, Y.F., Oryshchyn, S.V., Babizhetskii, V.S. et al. Crystal Structure of (Ti,Mo)12P7and Refined Phase Equilibria in the Ti–Mo–P System. Inorganic Materials 39, 555–561 (2003). https://doi.org/10.1023/A:1024084716531

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