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Aminomethylated calix[4]resorcinolarenes with NH groups on the upper rim of the molecule

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Russian Chemical Bulletin Aims and scope

Abstract

The reaction of calix[4]resorcinolarenes with N,N-dimethylethylenediamine and aqueous CH2O in a molar ratio of 1 : 5 : 5 affords calixarenes containing secondary amino groups arranged on the upper rim of the molecule. When the double amount (with respect to primary amine) of formalin is used (ratio of reactants 1 : 5 : 10), cavitands with four oxazinyl fragments are synthesized.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation

    N. I. Kharitonova, A. R. Burilov, M. A. Pudovik & A. I. Konovalov

Authors
  1. N. I. Kharitonova
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  2. A. R. Burilov
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  3. M. A. Pudovik
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  4. A. I. Konovalov
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Kharitonova, N.I., Burilov, A.R., Pudovik, M.A. et al. Aminomethylated calix[4]resorcinolarenes with NH groups on the upper rim of the molecule. Russian Chemical Bulletin 52, 725–727 (2003). https://doi.org/10.1023/A:1023983412277

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  • DOI: https://doi.org/10.1023/A:1023983412277

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