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First synthesis of dialkyl phosphonate derivatives of sesquiterpene α-methylene-γ-lactone

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Abstract

The stereoselective synthesis of two phosphorus-containing derivatives of the known guaianolide arglabin was carried out for the first time. The molecular structures of these products were established based on the spectroscopic data and the results of X-ray diffraction analysis of one of these compounds.

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Authors and Affiliations

  1. Institute of Phytochemistry, Ministry of Education and Sciences of the Republic of Kazakhstan, 4 ul. Gazalieva, 470032, Karaganda, Kazakhstan

    R. I. Jalmahanbetova, B. B. Rakhimova, A. T. Kulyjasov & S. M. Adekenov

  2. N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9 prosp. Akad. Lavrent"eva, 630090, Novosibirsk, Russian Federation

    V. A. Raldugin, I. Yu. Bagryanskaya, Yu. V. Gatilov, M. M. Shakirov & G. A. Tolstikov

Authors
  1. R. I. Jalmahanbetova
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  2. B. B. Rakhimova
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  3. V. A. Raldugin
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  4. I. Yu. Bagryanskaya
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  5. Yu. V. Gatilov
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  6. M. M. Shakirov
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  7. A. T. Kulyjasov
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  8. S. M. Adekenov
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  9. G. A. Tolstikov
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Jalmahanbetova, R.I., Rakhimova, B.B., Raldugin, V.A. et al. First synthesis of dialkyl phosphonate derivatives of sesquiterpene α-methylene-γ-lactone. Russian Chemical Bulletin 52, 748–751 (2003). https://doi.org/10.1023/A:1023943830932

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  • DOI: https://doi.org/10.1023/A:1023943830932

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