Abstract
Aminophosphonate calix[4]resorcinarene derivatives extract lanthanum and lutetium ions from aqueous solutions to chloroform much more efficiently than O,O-diethyl[(4-nitrophenyl)aminobenzyl] phosphonate does. In an excess of the metal ion in the aqueous phase with respect to the amounts of the extracting agent and sodium picrate, extraction occurs at the 1 : 1 molar ratio of the metal ion to extracting agent. In a twofold excess of the extracting agent and a considerable excess of sodium picrate over the metal ion, the composition of the extracted complex depends substantially on both the length of the alkyl substituent in the (AlkO)2P(O) group in the extracting agent and the number of lanthanide.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
I. M. Harrowfield, M. Mocerino, B. J. Peachey, B. W. Skelton, and A. H. White, J. Chem. Soc., Dalton Trans., 1996, 1687.
F. Arnaud-Neu, V. Böhmer, J.-F. Dozol, C. Grüttner, R. A. Jacobi, D. Kraft, O. Mauprivez, H. Rouquette, M.-J. Schwing-Weill, N. Simon, and W. Vogt, J. Chem. Soc., Perkin Trans. 2, 1996, 1175.
P. D. Beer, M. G. B. Drew, and M. I. Ogden, J. Chem. Soc., Dalton Trans., 1997,9, 1489.
H. Boerrigter, W. Verboom, and D. N. Reinhoudt, J. Org Chem., 1997, 62, 7148.
A. R. Burilov, N. I. Bashmakova, D. I. Kharitonov, I. L. Nikolaeva, M. A. Pudovik, V. S. Reznik, and A. I. Konovalov, Zh. Obshch. Khim., 1999, 69, 334 [Russ. J. Gen. Chem., 1999, 69, 323 (Engl. Transl.)].
A. Yu. Ziganshina, E. Kh. Kazakova, S. V. Fedorenko, A. R. Mustafina, and A. I. Konovalov, Zh. Obshch. Khim., 2001, 71, 1503 [Russ. J. Gen. Chem., 2001, 71, 1422 (Engl. Transl.)].
A. R. Mustafina, V. V. Skripacheva, E. Kh. Kazakova, N. A. Makarova, V. V. Kataev, L. V. Ermolaeva, and W. D. Habicher, J. Inclus. Phen. Macr. Chem., 2002, 42, 77.
S. J. Lyle and M. M. Rahman, Talanta, 1963, 10, 1177.
A. N. Pudovik, Dokl. Akad. Nauk SSSR, 1952, 83, 865 [Dokl. Chem., 1952 (Engl. Transl.)].
L. S. Serdyuk and V. S. Smirnaya, Zh. Anal. Khim., 1964, 19, 451 [J. Anal. Chem. USSR, 1964, 19 (Engl. Transl.)].
R. C. Helgeson, G. R. Weisman, J. L. Toner, T. L. Tarnowski, Y. Chao, J. M. Mayer, and D. J. Cram, J. Am. Chem. Soc., 1979, 101, 4928.
K. E. Koenig, G. M. Lein, P. Stuckler, T. Kaneda, and D. J. Cram, J. Am. Chem. Soc., 1979, 101, 3553.
Yu. I. Sal´nikov, A. N. Glebov, and F. V. Devyatov, Poliyadernye kompleksy v rastvorakh [Polynuclear Complexes in Solutions], Izd-vo KGU, Kazan, 1989, 287 pp. (in Russian).
J. M. Harrowfield, Lu Weimin, B. W. Skelton, and A. H. White, Aust. J. Chem., 1994, 47, 321.
J. M. Harrowfield, Lu Weimin, B. W. Skelton, and A. H. White, Aust. J. Chem., 1994, 47, 339.
U. Olsher, H. Feinberg, H. Frolow, and G. Shoham, Pure Appl. Chem., 1996, 68, 1195.
E. O. Out and A. D. Westland, Solv. Extr. Ion Exch., 1996, 14, 567.
G. Arena, A. Casnati, A. Contino, G. G. Lombardo, D. Sciotto, and R. Ungaro, Chem. Eur. J., 1999, 5, 738.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Fedorenko, S.V., Mustafina, A.R., Kazakova, E.K. et al. Sodium picrate effect on extraction of lanthanum and lutetium by aminophosphonate calix[4]resorcinarenes. Russian Chemical Bulletin 52, 562–566 (2003). https://doi.org/10.1023/A:1023934101373
Issue Date:
DOI: https://doi.org/10.1023/A:1023934101373