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Electroplating of Copperorganic Coatings from Perchlorate and Chloride Baths Containing ε-Caprolactam

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Abstract

The mechanisms of reactions, which occur both in solution and at the electrode during copper plating from perchlorate and chloride baths in the presence of ε-caprolactam capable of electrochemical polymerization are studied. It is shown that the formation of complexes by additive molecules with metal ions in the bulk of solution enhances its inhibiting effect and improves the quality of Cu-organic coatings. Complex formation also favors the increase in the adsorption of anions at the electrode. By varying the concentration of ε-caprolactam, it is possible to control the deposition rate and the composition and properties of the coatings.

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REFERENCES

  1. Kuznetsov, V.V., Skibina, L.M., Loskutnikova, I.N., and Sokolenko, A.I., Zashch. Met., 2003, vol. 39, no. 1, p. 88.

    Google Scholar 

  2. Kuznetsov, V.V., Skibina, L.M., Loskutnikova, I.N., et al., Zashch. Met., 2003, vol. 39, no. 2.

  3. Loshkarev, Yu.M., Omel'chenko, V.A., Vargalyuk, V.F., et al., Elektrokhimiya, 1974, vol. 10, no. 6, p. 723.

    Google Scholar 

  4. Kuznetsov, V.V., Skibina, L.M., Loskutnikova, I.N., and Kucherenko, S.S., Zashch. Met., 1998, vol. 34, no. 5, p. 521.

    Google Scholar 

  5. Lainer, V.I., Zashchitnye pokrytiya metallov (Protective Coatings on Metals), Moscow: Metallurgiya, 1974, p. 140.

    Google Scholar 

  6. Vyacheslavov, P.M., Novye elektrokhimicheskie pokrytiya (New Electrochemical Coatings), Leningrad: Lenizdat, 1972.

    Google Scholar 

  7. Galus, Z., Teoretyczne Podstawy Elektroanalizy Chemicznej (Theoretical Basics of Electrochemical Analysis), Warsaw: Panstowowe Wydawnictwo Naukowe, 1974.

    Google Scholar 

  8. Tatwawadi, S.V. and Bard, A.J., Analyt. Chem., 1964, vol. 36, no. 1, p. 2.

    Google Scholar 

  9. Kravtsov, V.I., Electrodnye protsessy v rastvorakh kompleksov metallov (Electrode Processes in Solutions of Metal Complexes), Leningrad: Leningrad University, 1969.

    Google Scholar 

  10. Ekilik, V.V. and Grigor'ev, V.P., Zashch. Met., 1977, vol. 13, no. 6, p. 690.

    Google Scholar 

  11. Skibina, L.M., Kuznetsov, V.V., and Sukholentsev, E.A., Zashch. Met., 2001, vol. 37, no. 2, p. 182.

    Google Scholar 

  12. Frumkin, A.N., in Osnovnye voprosy sovremennoi teoreticheskoi elektrokhimii (Basic Problems of Modern Theoretical Electrochemistry), Frumkin, A.N., Ed., Moscow: Mir, 1965, p. 302.

    Google Scholar 

  13. Lorenz, W., Z. Elektrochem., 1955, vol. 49, no. 5, p. 730.

    Google Scholar 

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Authors and Affiliations

  1. Rostov State University, ul. Zorge 7, Rostov-na-Donu, Russia

    L. M. Skibina, V. V. Kuznetsov & A. I. Sokolenko

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  1. L. M. Skibina
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  2. V. V. Kuznetsov
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  3. A. I. Sokolenko
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Skibina, L.M., Kuznetsov, V.V. & Sokolenko, A.I. Electroplating of Copperorganic Coatings from Perchlorate and Chloride Baths Containing ε-Caprolactam. Protection of Metals 39, 235–240 (2003). https://doi.org/10.1023/A:1023911002940

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