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Preparation and characterization of 1-butyl-3-methylimidazolium tetrakis(3,5-bis(trifluoromethyl) phenyl)borate, [bmim]BARF

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Abstract

Attempts to prepare novel air and moisture stable room-temperature ionic liquids have afforded a new 1,3-dialkylimidazolium tetraarylborate salt: 1-butyl-3-methylimidazolium tetrakis(3,5-bis(trifluoromethyl)phenyl)borate, [bmim]BARF, 1. Crystal data: C80 H 54 b 2F48N4, monoclinic space group P2(1)/n, a = 21.2622(17) Å, b = 15.8037(13) Å, c = 26.227(2) Å, β = 101.841(2) ○, V = 8625.3(12) Å3, Z = 1.544.

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Authors and Affiliations

  1. Department of Chemistry, Saint Mary's University, Nova Scotia, Canada

    Jeremy Finden, Gavin Beck, Andrea Lantz & Robert D. Singer

  2. Department of Chemistry, University of South Florida, Tampa, Florida, 33620-5250

    Rosa Walsh & Michael J. Zaworotko

Authors
  1. Jeremy Finden
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  2. Gavin Beck
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  3. Andrea Lantz
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  4. Rosa Walsh
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  5. Michael J. Zaworotko
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  6. Robert D. Singer
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Correspondence to Robert D. Singer.

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Finden, J., Beck, G., Lantz, A. et al. Preparation and characterization of 1-butyl-3-methylimidazolium tetrakis(3,5-bis(trifluoromethyl) phenyl)borate, [bmim]BARF. Journal of Chemical Crystallography 33, 287–295 (2003). https://doi.org/10.1023/A:1023885212233

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