Abstract
A new apparatus for the measurement of equilibria and dynamics for gas-phase adsorption systems is utilized to examine the adsorption of carbon dioxide on BPL activated carbon. The apparatus has a flow-through configuration. For dynamics, with constant inlet flow, pressure within the adsorbent-containing section is varied sinusoidally, and the time-dependent outlet flow rate is measured to determine an amplitude ratio and phase lag. Studies are made of temperature effects and particle size effects. Results are compared with several mathematical models. Frequency response data show that the BPL system follows surface (or micropore) diffusion kinetics. The rate of adsorption for the activated carbon is found to be only weakly dependent on the bulk particle size.
Similar content being viewed by others
References
Alpay, E. and D.M. Scott, "The Linear Driving Force Model for Fast-Cycle Adsorption and Desorption in a Spherical Particle," Chem. Eng. Sci., 47, 499-502 (1991).
Boniface, H.A. and D.M. Ruthven, "Chromatographic Adsorption with Sinusoidal Input," Chem. Eng. Sci., 40, 2053-2061 (1985).
Bourdin, V., P.H. Grenier, F. Meunier, and L.M. Sun, "Thermal Fre-quency Response Method for the Study of Mass-Transfer Kinetics in Adsorbents," AIChE J., 42, 700-712 (1996).
Bülow, M. and A. Micke, "Determination of Transport Coefficients in Microporous Solids," Adsorption, 1,29-48 (1995).
Carta, G., "The Linear Driving Force Approximation for Cyclic Mass Transfer in Spherical Particles," Chem. Eng. Sci., 48, 622-625
Do, D.D., Adsorption Analysis: Equilibria and Kinetics, Imperial College Press, London, 1998.
Grenier, P.H., A. Malka-Edery, and V. Bourdin, "A Temperature Fre-quency Response Method for Adsorption Kinetics Measurement," Adsorption, 5, 135-143 (1999).
Grzegorczyk, D.S. and G. Carta, "Frequency Response of Liquid-Phase Adsorption on Polymeric Adsorbents," Chem. Eng. Sci., 52, 1589-1608 (1997).
Jordi, R.D. and D.D. Do, "Analysis of the Frequency Response Method for Sorption Kinetics in Bidispersed Structured Sorbents," Chem. Eng. Sci., 48, 1103-1130 (1993).
Jordi, R.D. and D.D. Do, "Analysis of the Frequency Response Method Applied to Non-Isothermal Sorption Studies," Chem. Eng. Sci., 49, 957-979 (1994).
Kärger, J. and D.M. Ruthven, Diffusion in Zeolites and Other Micro-porous Solids, Wiley, New York, 1992.
Li, Y., D. Willcox, and R.D. Gonzalez, "Determination of Rate Constants by the Frequency Response Method: CO on Pt/SiO2," AIChE J., 35, 423-428 (1989).
Li, C. and B.A. Finlayson, "Heat Transfer in Packed Beds-A Reevaluation," Chem. Eng. Sci., 32, 1055-1066 (1977).
Mugge, J., H. Bosch, and T. Reith, "Measuring and Modeling Gas Adsorption Kinetics in Single Porous Particles," Chem. Eng. Sci., 56, 5351-5360 (2001).
Nakao, S. and M. Suzuki, "Mass Transfer Coefficient in Cyclic Adsorption and Desorption," J. Chem. Eng. Japan, 16, 114-119 (1983).
Onyestyak, G. and L.V.C. Rees, "Frequency Response Study of Ad-sorbate Mobilities of Different Character in Various Commercial Adsorbents," J. Phys. Chem. B, 103, 7469-7479 (1999).
Park, I.S., M. Petkovska, and D.D. Do, "Frequency Response of an Adsorber with Modulation of the Inlet Molar Flow-Rate-I. A Semi-Batch Adsorber," Chem. Eng. Sci., 53, 819-832 (1998a).
Park, I.S., M. Petkovska, and D.D. Do, "Frequency Response of an Adsorber with Modulation of the Inlet Molar Flow-Rate-II. A Continuous Flow Adsorber," Chem. Eng. Sci., 53, 833-843 (1998b).
Petkovska, M. and D.D. Do, "Nonlinear Frequency Response of Ad-sorption Systems: Isothermal Batch and Continuous Flow Adsor-bers," Chem. Eng. Sci., 53, 3081-3097 (1998).
Petkovska, M. and D.D. Do, "Use of Higher-Order Frequency Re-sponse Functions for Identification of Nonlinear Adsorption Ki-netics: Single Mechanisms under Isothermal Conditions," Nonlin. Dynam., 21, 353-376 (2000).
Polinski, L.M. and L.M. Naphtali, "A Novel Technique for Character-ization of Adsorption Rates on Heterogeneous Surfaces," J. Phys.Chem., 67, 369-375 (1963).
Prasetyo, I. and D.D. Do, "Adsorption Rate of Methane and Carbon Dioxide on Activated Carbon by the Semi-Batch Constant Molar Flow Rate Method," Chem. Eng. Sci., 53, 3459-3467 (1998).
Reich, R., W.T. Ziegler, and K.A. Rogers, "Adsorption of Methane, Ethane, and Ethylene Gases and Their Binary and Ternary Mix-tures and Carbon Dioxide on Activated Carbon at 212-301 K and Pressures to 35 Atmospheres," Ind. Eng. Chem. Proc. Des. Dev., 19, 336-344 (1980).
Shen, D.M. and L.V.C. Rees, "Study of Fast Diffusion in Zeolites Using a Higher Harmonic Frequency-Response Method," J. Chem. Soc., Faraday Trans., 90, 3011-3015 (1994).
Sun, L.M., F. Meunier, and J. Kärger, "On the Heat Effect in Measure-ments of Sorption Kinetics by the Frequency Response Method," Chem. Eng. Sci., 48, 715-722 (1993a).
Sun, L.M., F. Meunier, and P.H. Grenier, "Frequency Response for Nonisothermal Adsorption in Biporous Pellets," Chem. Eng. Sci., 49, 373-381 (1993b).
Suzuki, M. Adsorption Engineering, Elsevier Science Publishing Company, New York, 1990.
Sward, B.K., Ph.D. dissertation, University of Virginia, 2001.
Taqvi, S.M. and M.D. LeVan, "Role of Convection and Diffusion in a Single Pore with Adsorptive Walls," Adsorption, 2, 299-309 (1996).
Van-Den-Begin, N., L.V.C. Rees, J. Caro, M. Bülow, M. Hunger, and J. Kärger, "Diffusion of Ethane in Silicalite-1 by Frequency Re-sponse, Sorption Uptake and Nuclear Magnetic Resonance Tech-niques," J. Chem. Soc., Faraday Trans. I, 85, 1501-1509 (1989).
Yasuda, Y. and A. Yamamoto, "Zeolitic Diffusivities of Hydrocar-bons by the Frequency Response Method," J. Catal., 93, 176-181 (1985).
Yasuda, Y., "Frequency Response Method for Investigation of Gas-Surface Dynamic Phenomena," Heterogen. Chem. Rev., 1, 103-124 (1994).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Sward, B.K., LeVan, M.D. Frequency Response Method for Measuring Mass Transfer Rates in Adsorbents via Pressure Perturbation. Adsorption 9, 37–54 (2003). https://doi.org/10.1023/A:1023863213893
Issue Date:
DOI: https://doi.org/10.1023/A:1023863213893