Abstract
The formation of alumina particles from aluminum salts in the presence of poly(1-vinylimidazole) was investigated by quantitative 27Al NMR, potentiometry and FTIR spectra. The interaction of poly(1-vinylimidazole) with aluminum chloride and nitrate in an aqueous medium stabilizes [AlO4Al12(OH)24]7+ and less ordered polymeric particles. The addition of NaOH (NaOH: Al ≥ 2) results in water-insoluble organic/inorganic hydrogen-bonded composites. Stabilization of the complexes is realized by cooperative hydrogen N···H—O—Al bonds, without N → Al donor-acceptor interactions.
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Annenkov, V., Filina, E., Danilovtseva, E. et al. Aluminum Complexes with a Donor Polymer: New Route to Organic/Inorganic Polymer Hybrids. Journal of Sol-Gel Science and Technology 27, 163–166 (2003). https://doi.org/10.1023/A:1023798400941
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DOI: https://doi.org/10.1023/A:1023798400941