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Polymerization Behaviour of Organically Modified Titanium Alkoxides in Solution

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Abstract

Modified titanium alkoxides with polymerizable organic ligands allow the synthesis of copolymers consisting of hybrid organic/inorganic networks. In this work titanium based-precursors were characterized in relation to the polymerization behaviour of the organic matrix. Alkoxide sols were prepared by reaction of methacrylic acid, itaconic acid anhydride, isoeugenol, p-vinylbezoic acid, p-vinylphenylacetic acid, and acetoxyacetomethacrylate with titanium tetraisopropoxide and titanium tetraethoxide. Polymerization reactions were carried out in solution using UV-irradiation and a redox-system of dibenzoylperoxide/N, N-dimethyl-p-toluidine as radical initiators. Especially for chemical activation some complexes showed high reactivity similar to silica-based methacrylates. The systems investigated are capable of acting as adhesive promoters between metal and polymer in dental applications.

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Authors and Affiliations

  1. Dept. of Functional Materials in Medicine & Dentistry, ZMK-Clinic, University of Wurzburg, Pleicherwall 2, Wurzburg, Germany, D-97070

    Uwe Gbureck, Jörn Probst & Roger Thull

Authors
  1. Uwe Gbureck
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  2. Jörn Probst
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  3. Roger Thull
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Gbureck, U., Probst, J. & Thull, R. Polymerization Behaviour of Organically Modified Titanium Alkoxides in Solution. Journal of Sol-Gel Science and Technology 27, 157–162 (2003). https://doi.org/10.1023/A:1023746416871

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  • DOI: https://doi.org/10.1023/A:1023746416871

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