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A Statistical Approach to Estimate Spatial Distributions of Wet Deposition in Germany

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Abstract

The correct spatial interpolation from a few available point measurements of wet deposition - which contributes a major partto total deposition - is very important for the determination ofa possible exceeding of critical loads: A wide spatial variability is a property of both deposition and critical loads.For this purpose, the meteorological variables having relevant influence on wet deposition and being available from routine measurements were used as input data for a statistical model forthe estimation of wet deposition. Those variables are precipitation amount, preceding dry period, wind direction andseason. The results obtained from the developed model were validated using measurements from routine monitoring stations inGermany for daily wet deposition rates of the major anions andcations. After description of model development and verification,the application of the model is presented exemplarily for sulfate,chloride and nitrate. Therefore daily precipitation data from afew representative monitoring stations and additional informationabout wind direction from meteorological maps were used as modelinput. As a result, reliable point estimates for wet depositionwere available in addition to the measured data, thus allowingspatial interpolation with higher accuracy. The resulting wetdeposition maps reveal that the critical loads for theinvestigated substances are already exceeded in some areas ofGermany, particularly when the additional input from dry andoccult (fog and cloud) deposition is taken into account. Using allavailable daily precipitation data in an annual routine, depositionmaps could be available with high spatial resolution (<10 km).

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References

  • Aherne, J. and Farrell, E. P.: 2002, ‘Deposition of sulphur, nitrogen and acidity in precipitation over Ireland: Chemistry, spatial distribution and long-term trends’ Atmosph. Environ. 36, 1379-1389

    Google Scholar 

  • Asman, W. A. H. and Van Jaarsveld, A. A.: 1992, ‘A variable - Resolution transport model applied for NHx in Europe’ Atmosph. Environ. 26A, 445-464.

    Google Scholar 

  • Bobbink, R. and Roelofs, J. G. M.: 1995, ‘Nitrogen critical loads for natural and semi-natural ecosystems: The empirical approach’ Water, Air, and Soil Pollut. 58, 122-178.

    Google Scholar 

  • Bull, K. R.: 1992, ‘An introduction to critical loads’ Environ. Pollut. 77, 173-176.

    Google Scholar 

  • Bull, K. R.: 1995, ‘Critical loads - Possibilities and constraints’ Water, Air, and Soil Pollut. 85, 201-212.

    Google Scholar 

  • Busch, A. U., Brechtel, H. M. and Urfer, W.: 1994, ‘Statistical Methods for the Evaluation of Hydrological Parameters for Landuse Planning’ in V. Barnett and F. K. Turkman (eds), Statistics for the Environment: Water-related Issues, Wiley, Chichester, U.K., Chapter 18, pp. 319-344.

    Google Scholar 

  • Busch, A. U.: 1995, ‘Modellierung der nassen Deposition in Abhängigkeit von der Witterung’ in E. Kublin and R. Lasser (eds), Tagungsberichte der Arbeitsgruppe Ökologie, Internationale Biometrische Gesellschaft Deutsche Region, German Region of the International Biometric Society, Mannheim, Germany, Vol. 6, pp. 87-107.

    Google Scholar 

  • Busch, A. U. and Vautz, W.: 1995, ‘Ermittlung spezifischer Konzentrationsverläufe atmos-phärischer Spurenbestandteile in Niederschlägen als Methode zur Abschätzung des flächenhaften Stoffeintrags in den Boden unter Anwendung statistischer Methoden’ Research Report 302-02-006, Federal Environmental Agency, Berlin, Germany.

    Google Scholar 

  • CCE: 1995, Calculation and Mapping of Critical Loads in Europe: Status Report 1995, R. J. Downing, J.-P. Hettelingh and P. A.M. de Smet (eds), National Institute of Public Health and Environmental Protection - Rijksinstituut voor Volksgezondheid en Milieuhygiene (RIVM), Report No. 259101003, Bilthoven, The Netherlands.

  • Cohn, R. D. and Dennis, R. L.: 1994, ‘The evaluation of acid deposition models using principal component spaces’Atmosph. Environ. 28, 2531-2543.

    Google Scholar 

  • Draajers, G. P. J., Van Leeuwen, E. P., De Jong, P. G. H. and Erisman, J. W.: 1996, ‘Base Cation Deposition in Europe: Acid Neutralization Capacity and Contribution to Forest Nutrition’ RIVM Report No. 722-108-009, Bilthoven, The Netherlands.

    Google Scholar 

  • Durana, N., Casado, H., Ezcurra, A., Garcia, C., Lacaux, J. P. and Van Dinh, P.: 1992, ‘Experimental study of the scavenging process by means of a sequential precipitation collector, preliminary results’ Atmosph. Environ. 26A, 2437-2443.

    Google Scholar 

  • Eilers, P. H. C.: 1991, ‘Penalized regression in action: Estimating pollution roses from daily averages’ Environmetrics 91, 25-47.

    Google Scholar 

  • Fowler, D., Leith, I. D., Binnie, J., Crossley, A., Inglis, D. W. F., Choularton, T. W., Gay, M., Longhurst, J. W. S. and Conland, D. E.: 1995, ‘Orographic enhancement of wet deposition in the United Kingdom: Continuous monitoring’ Water, Air, and Soil Pollut. 85, 2107-2112.

    Google Scholar 

  • Hicks, B. B., McMillan, R., Turner, R. S., Holdren Jr., G. R. and Strickland, T. C.: 1993, ‘A national critical loads framework for atmospheric deposition effects assessment: III. Depositioncharacterization’ Environ. Manage. 17, 343-353.

  • Hornung, M., Sutton, M. A. and Wilson, R. B. (eds.): 1994, Mapping and Modelling of Critical Loads for Nitrogen - A Workshop Report, Institute of Terrestrial Ecology, Bush Estate, United Kingdom.

    Google Scholar 

  • Inglis, D. W. F., Choularton, T. W., Wicks, A. J., Fowler, D., Leith, I. D., Werkman, B. and Binnie, J.: 1995, ‘Orographic enhancement of wet deposition in the United Kingdom: Case studies and modelling’ Water, Air, and Soil Pollut. 85, 2119-2124.

    Google Scholar 

  • Kane, M. M., Rendell, R. and Jickells, T. D.: 1994, ‘Atmospheric scavenging processes over the North Sea’ Atmosph. Environ. 28, 2523-2540.

    Google Scholar 

  • Lee, D. S., Kingdon, R. D., Pacyny, J. M., Bouwman, A. F. and Tegen, I.: 1999, ‘Modelling base cations in Europe - Sources, transport and deposition of calcium’ Atmosph. Environ. 33, 2241-22565.

    Google Scholar 

  • Lövblad, G., Erisman, J.W. and Fowler, D.: 1993, ‘Models and Methods for the Quantification of Atmospheric Input to Ecosystems’ Proceedings of the Nordic Council/EMEP/BIATEX Workshop, Göteborg, Sweden, 3-6 November 1992.

  • Miller, E. K., Friedland, A. J., Arons, E. A., Mohnen, V. A., Battles, J. J., Panek, J. A., Kadlecek, J. and Johnson, A. H.: 1993, ‘Atmospheric deposition to forests along an elevation gradient at Whiteface Mountain, NY, U.S.A.’ Atmosph. Environ. 27A, 2121-2136.

    Google Scholar 

  • Nagel, H.-D. and Gregor, H.-D.: 1999, Ökologische Belastungsgrenzen - Critical Loads and Levels, Springer-Verlag, Berlin, Germany.

    Google Scholar 

  • Nilson, J.: 1986, ‘Critical Loads for Nitrogen and Sulphur’ in Miljørapport 1986, Vol. 11. Nordic Council of Ministers, Copenhagen, Denmark.

    Google Scholar 

  • Pruppacher, H. R. and Klett, J. D.: 1996, Microphysics of Clouds and Precipitation, Kluwer Academic Publishers, Dordrecht, The Netherlands.

    Google Scholar 

  • Sander, G., Lelieveld, J. and Crutzen, P. J.: 1995, ‘Modelling of the nighttime nitrogen and sulfur chemistry in size resolved droplets of an orographic cloud’ J. Atmosph. Chem. 20, 89-116.

    Google Scholar 

  • Sanders, G. E., Skärby, L., Ashmore, M. R. and Fuhrer, J.: 1995, ‘Establishing critical levels for the effects of air pollution on vegetation’ Water, Air, and Soil Pollut. 85, 189-200.

    Google Scholar 

  • Van den Hout, K. D., Bakker, D. J., Berdowski, J. J.M., Van Jaarsveld, J. A., Reinds, G. J., Bril, J., Breeuwsma, A., Groenenberg, J. E., De Vries, W., Van Pagee, J. A., Villars, M. and Sliggers C. J.: 1999, 'The impact of atmospheric deposition of non-acidifying substances on the qualoty of European forest soild and the North Sea’ Water, Air, and Soil Pollut. 109, 357-396.

    Google Scholar 

  • Vautz, W.: 1991, ‘Calculation of Concentration Distributions for Atmospheric Pollutants from Continuously Measured Data’ in M. Hälker and A. Jaeschke (eds), Computer Science for Environmental Protection, Springer-Verlag, Berlin, Germany, pp. 48-59.

    Google Scholar 

  • Vautz, W., Schilling, M., Goncalves, F. L. T., Colci, M. C., Massambani, O. and Klockow, D.: 1995, ‘Preliminary analysis of atmospheric scavenging processes in the industrial region of Cubatäo, Southeastern Brazil’ Water, Air, and Soil Pollut. 85, 1973-1978.

    Google Scholar 

  • Wintermeyer, D. and Klockow, D.: 1990, ‘Deposition von Säuren und Salzen in der Bundesrepublik Deutschland 1983-1987’ in VDI Berichte, Vol. 837: Wirkungen von Luftverunreinigungen auf Böden, Teil 1: Einträge - Bewertung - Regulierung, VDI-Verlag, Düsseldorf, Germany, pp. 305-332.

    Google Scholar 

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Vautz, W., Busch, A.U., Urfer, W. et al. A Statistical Approach to Estimate Spatial Distributions of Wet Deposition in Germany. Water, Air, & Soil Pollution 145, 215–238 (2003). https://doi.org/10.1023/A:1023676011565

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