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31P NMR Study of Complexation between Thallium(III) and Diethylenetriaminopentakis(methylenephosphonic Acid)

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Abstract

Aqueous solutions containing thallium(III) and diethylenetriaminopentakis(methylenephosphonic acid) (DTPP, H10Dtpph) in a ratio of 1 : 1 were studied by 31P NMR spectroscopy in a pH range from 4 to 11. Complexation between DTPP and thallium in aqueous solutions gave complexes [TlH n Dtpph]n – 7, which are highly stable on the NMR time scale. Each complex contains three nonequivalent phosphonic groups characterized by 2,3 J(31Р,Tl) spin–spin coupling constants of 560 to 310 Hz. All the five phosphonic groups of DTPP are involved in coordination. The structure of the complex [TlH n Dtpph]n – 7 was proposed.

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Authors and Affiliations

  1. Mendeleev University of Chemical Technology, Miusskaya pl. 9, Moscow, 125190, Russia

    I. A. Popova

  2. Moscow State University of Food Production, Volokolamskoe sh. 11, Moscow, 125080, Russia

    K. I. Popov

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  1. I. A. Popova
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  2. K. I. Popov
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Popova, I.A., Popov, K.I. 31P NMR Study of Complexation between Thallium(III) and Diethylenetriaminopentakis(methylenephosphonic Acid). Russian Journal of Coordination Chemistry 29, 307–309 (2003). https://doi.org/10.1023/A:1023663431918

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  • DOI: https://doi.org/10.1023/A:1023663431918

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