Abstract
Bis(2,6-(2′,6′-diisoproylanil)diformyl-4-chloro-phenolate) nickel(II) was prepared by the reaction of 2,6-(2′,6′-diisoproylanil)diformyl-4-chloro-phenol with nickel chloride. The title complex crystallized in P21/c, with cell dimensions a = 9.962(2) Å, b = 12.087(3) Å, c = 24.445(6) Å, and β = 97.032(5)○, giving a volume of 2921.4(13) Å3. The bis(2,6-(2′,6′-diisoproylanil)diformyl-4-chloro-phenolate) nickel(II) adapts an ideal parallelogram, in which the Ni atom is coordinated with two phenolic oxygen atoms [O(1), O(1A)] and two imino nitrogen atoms [N(1), N(1A)].
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Han, L., Sun, WH., Wang, L. et al. Bis(2,6-(2′,6′-diisoproylanil)diformyl-4-chloro-phenolate) nickel(II). Journal of Chemical Crystallography 33, 159–163 (2003). https://doi.org/10.1023/A:1023509007651
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DOI: https://doi.org/10.1023/A:1023509007651