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Iodine and cymantrenyl regioselective exchange in the η5-IC5H4(CO)2Fe-η1,η5-C5H4Mn(CO)3 complex under cross-coupling conditions

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Abstract

The reaction of η5-IC5H4(CO)2Fe-η1,η5-C5H4Mn(CO)3 with Me3SiC≡CSiMe3 (2 : 1) in the presence of Pd(MeCN)2Cl2 afforded the I(CO)2Fe(C5H4—C5H4)Mn(CO)3 complex generated through migrations of the I atom from the Cp ring to the Fe atom and of the C5H4Mn(CO)3 group from the Fe atom to the Cp ring.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    T. Yu. Orlova, Yu. S. Nekrasov, P. V. Petrovskii & M. G. Ezernitskaya

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  1. T. Yu. Orlova
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  2. Yu. S. Nekrasov
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  3. P. V. Petrovskii
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  4. M. G. Ezernitskaya
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Orlova, T.Y., Nekrasov, Y.S., Petrovskii, P.V. et al. Iodine and cymantrenyl regioselective exchange in the η5-IC5H4(CO)2Fe-η1,η5-C5H4Mn(CO)3 complex under cross-coupling conditions. Russian Chemical Bulletin 52, 410–413 (2003). https://doi.org/10.1023/A:1023471118927

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  • DOI: https://doi.org/10.1023/A:1023471118927

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