Abstract
Low-temperature (T = 80 K) interaction of the sublimed layers of meso-mono-4-pyridyltriphenylporphyrinatoiron(ii) (FeMPyTPP) with dioxygen was studied by IR and electronic absorption spectroscopies. Unlike the meso-tetraphenylporphyrinatoiron(ii) (FeTPP) layers, coordination of O2 with FeMPyTPP produces extra-complexes of two types: in the first complex one of the axial sites is free, while in the second complex an axial site is occupied by the pyridine group of the adjacent molecule. The results obtained indicate self-assembly of the FeMPyTPP molecules through coordination bonds between the iron atom and pyridine group of the adjacent molecule in the layer. The bonding of O2 by the sublimed FeMPyTPP layers differs substantially from that by the FeTPP layers, which rapidly loose their ability of oxygen bonding at room temperature.
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Kurtikyan, T.S., Kazaryan, R.K. & Madakyan, V.N. Self-assembly of meso-mono-4-pyridyltriphenylporphyrinatoiron(ii) in sublimed layers. Interaction with molecular oxygen. Russian Chemical Bulletin 52, 394–397 (2003). https://doi.org/10.1023/A:1023415001180
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DOI: https://doi.org/10.1023/A:1023415001180