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Synthesis and Structure of Bis(tetraphenylantimony) Tetrafluorophthalate

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Abstract

Oxidation of pentaphenylantimony with atmospheric oxygen in toluene on heating gives μ-oxo-bis(tetraphenylantimony) (yield 63%). Its reaction with tetrafluorophthalic anhydride gives bis(tetraphenylantimony) tetrafluorophthalate (yield 94%). According to single-crystal X-ray diffraction data, the antimony atoms in the molecule of bis(tetraphenylantimony) tetrafluorophthalate have a distorted trigonal bipyramidal coordination with the following geometries: Sb-O bond lengths 2.357(3) and 2.283(3) Å, Sb-C bond lengths 2.108(4)-2.141(4) and 2.100(5)-2.158(4) Å, and CSbO angles 177.42(14)° and 176.18(14)°.

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Authors and Affiliations

  1. Blagoveshchensk State Pedagogical University, Blagoveshchensk, Russia

    V. V. Sharutin, O. K. Sharutina, E. A. Bondar', V. S. Senchurin, A. P. Pakusina, Yu. V. Gatilov, N. Yu. Adonin & V. F. Starichenko

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  1. V. V. Sharutin
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  2. O. K. Sharutina
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  3. E. A. Bondar'
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  4. V. S. Senchurin
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  5. A. P. Pakusina
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  6. Yu. V. Gatilov
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  7. N. Yu. Adonin
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  8. V. F. Starichenko
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Sharutin, V.V., Sharutina, O.K., Bondar', E.A. et al. Synthesis and Structure of Bis(tetraphenylantimony) Tetrafluorophthalate. Russian Journal of General Chemistry 72, 1920–1924 (2002). https://doi.org/10.1023/A:1023411228493

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  • DOI: https://doi.org/10.1023/A:1023411228493

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