Abstract
Reactions of ethyl and tert-butyl phosphorodiamidites with chloroacetone, bromoacetone, and α-chloroethyl acetate were studied. The reaction pathway is determined by the structure of the intermediate quasiphosphonium compound responsible for the formation of the Arbuzov product as well as for the occurrence of the amonalous reaction yielding vinyl phosphate.
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Sal'keeva, L.K., Nurmaganbetova, M.T., Kurmanaliev, O.S. et al. Reactions of Phosphorodiamidous Acid Esters with α-Halocarbonyl Compounds. Russian Journal of General Chemistry 72, 1760–1763 (2002). https://doi.org/10.1023/A:1023397330794
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DOI: https://doi.org/10.1023/A:1023397330794