Skip to main content
SpringerLink
Log in

Testing the Product Accumulation in the Porous Volume of Hydrophobized Electrodes during Electrosynthesis by Cyclic Voltammetry

  • Published:
Russian Journal of Electrochemistry Aims and scope Submit manuscript

Abstract

Cyclic voltammograms (CVA) for the hydrogen peroxide electrosynthesis from oxygen in gas-diffusion hydrophobized electrodes (GHE) of acetylene black A437-E, furnace black P805-E, and their mixtures in an alkaline electrolyte are compared in order to test the product accumulation in their porous volumes. The increase in the area of the peak in an anodic branch of CVA during hydrogen peroxide accumulation depends on the GHE type. The removal of hydrogen peroxide in the GHE is facilitated by using a mixture of blacks. The CVA method is convenient for testing the product accumulation in the porous volume.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Kornienko, G.V., Kenova, T.A., Saltykov, Yu.V., et al., Elektrokhimiya, 1998, vol. 34, p. 633.

    Google Scholar 

  2. Saltykov, Yu.V., Kornienko, G.V., Kenova, T.A., and Kornienko, V.L., Elektrokhimiya, vol. 36, p. 1483.

  3. Organic Electrochemistry, Baizer, M.M., Ed., New York: Marcel Dekker, 1973.

    Google Scholar 

  4. Saltykov, Yu.V., Kenova, T.A., and Kornienko, V.L., Elektrokhimiya, 1996, vol. 32, p. 107.

    Google Scholar 

  5. Chaenko, N.V., Kornienko, V.L., Turenko, L.T., et al., Zh. Prikl. Khim. (Leningrad), 1989, vol. 62, p. 57.

    Google Scholar 

  6. Kenova, T.A., Abolin, O.E., and Kornienko, V.L., Zh. Prikl. Khim. (Leningrad), 1991, vol. 64, p. 670.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Chemistry and Chemical Technology, Siberian Division, Russian Academy of Sciences, Krasnoyarsk, Russia

    V. L. Kornienko & Yu. V. Saltykov

Authors
  1. V. L. Kornienko
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yu. V. Saltykov
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kornienko, V.L., Saltykov, Y.V. Testing the Product Accumulation in the Porous Volume of Hydrophobized Electrodes during Electrosynthesis by Cyclic Voltammetry. Russian Journal of Electrochemistry 39, 413–414 (2003). https://doi.org/10.1023/A:1023370224746

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1023370224746

Keywords

Search

Navigation