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Kinetics and Mechanism of Monomolecular Heterolysis of Commercial Organohalogen Compounds: XXXI. Solvent Effect on the Rate of 1-Methyl-1-chlorocyclopentane Heterolysis. Correlation Analysis of Solvation Effects

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Abstract

Heterolysis of 1-methyl-1-chlorocyclopentane in protic and aprotic solvents occurs by the E1 mechanism. The reaction rate in aprotic solvents or in a set of protic and aprotic solvents is satisfactorily described by the parameters of the polarity and electrophilicity or ionizing power of the solvents. In protic solvents, the reaction rate grows with increasing polarity or ionizing power of the solvent and decreases with increasing nucleophilicity.

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Authors and Affiliations

  1. Kiev Polytechnic Institute, National Technical University of Ukraine, Kiev, Ukraine

    G. F. Dvorko, I. V. Koshchii, A. M. Prokopets & E. A. Ponomareva

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  1. G. F. Dvorko
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  2. I. V. Koshchii
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  3. A. M. Prokopets
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  4. E. A. Ponomareva
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Dvorko, G.F., Koshchii, I.V., Prokopets, A.M. et al. Kinetics and Mechanism of Monomolecular Heterolysis of Commercial Organohalogen Compounds: XXXI. Solvent Effect on the Rate of 1-Methyl-1-chlorocyclopentane Heterolysis. Correlation Analysis of Solvation Effects. Russian Journal of General Chemistry 72, 1797–1804 (2002). https://doi.org/10.1023/A:1023357716681

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