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Separation of lithium isotopes by elution chromatography with an AB18C6 bonded Merrifield peptide resin

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Abstract

Cation exchange chromatographic separation of lithium isotopes was carried out with an 4'-aminobenzo-18-crown-6(AB18C6) bonded Merrifield peptide resin. This resin has a capacity of 2.25 meq/g dry resin. Upon column elution chromatography, a single stage separation factor of 1.0095, was obtained by the Glueckauf theory from the elution curve and isotopic assays. The heavier isotope, 7Li, was concentrated in the resin phase, while the lighter one, 6Li, concentrated in the solution phase.

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References

  1. C. J. Pedersen, J. Am. Chem. Soc., 89 (1967) 7017.

    Google Scholar 

  2. S. Kitazawa K. Kimura H. Yano T. Shono, J. Am. Chem. Soc., 106 (1984) 6978.

    Google Scholar 

  3. R. W. Conn, J. Nucl. Sci. Technol., 26 (1975) 391.

    Google Scholar 

  4. H. Takeuchi T. Oi M. Hosoe, Separ. Sci. Technol., 34 (1999) 545.

    Google Scholar 

  5. H. Ogino T. Oi, Separ. Sci. Technol., 31 (1996) 1215.

    Google Scholar 

  6. D. W. Kim B. K. Jeon C. S. Kim Y. S. Jeon, J. Radioanal. Nucl. Chem., 245 (2000) 509.

    Google Scholar 

  7. J. E. Powell, J. Inorg. Nucl. Chem., 24 (1962) 183.

    Google Scholar 

  8. T. Oi K. Shimizu S. Tayama M. Hosoe, Separ. Sci. Technol., 34 (1999) 805.

    Google Scholar 

  9. D. W. Kim H. I. Kim M. S. Kim K. Y. Choi S. H. Kown J. S. Shin J. S. Kim, J. Radioanal. Nucl. Chem., 247 (2001) 385.

    Google Scholar 

  10. Y. S. Jeon M. Y. Suh J. S. Kim, A Study of Lithium Isotope Separation, KAERI/ RR-1860/99, 1999, p. 1.

  11. K. Dorfner, Ionenaustauscher, Dritte Aufl., Walter de Gruyter, Berlin, 1970, p. 47.

    Google Scholar 

  12. K. Dorfner (Ed.), Ion Exchangers, in: Appendix I, Walter de Gruyter, Berlin, 1991, p. 1451.

  13. E. Glueckauf, Trans. Faraday Soc., 51 (1955) 34.

    Google Scholar 

  14. E. Glueckauf, Trans. Faraday Soc., 54 (1958) 1203.

    Google Scholar 

  15. T. Oi K. Kawada M. Hosoe H. Kakihana, Separ. Sci. Technol., 26 (1991) 1353.

    Google Scholar 

  16. K. Ooi Y. Miyai Y. Makita H. Kanoh, Separ. Sci. Technol., 34 (1999) 1133.

    Google Scholar 

  17. S. Fujine K. Saito K. Shiba, J. Nucl. Sci. Technol., 20 (1983) 439.

    Google Scholar 

  18. D. A. Lee G. M. Begun, J. Am. Chem. Soc., 81 (1959) 2332.

    Google Scholar 

  19. A. R. Gupta, Separ. Sci. Technol., 14 (1979) 843.

    Google Scholar 

  20. D. A. Lee, J. Am. Chem. Soc., 83 (1961) 1801.

    Google Scholar 

  21. D. A. Lee, J. Inorg. Nucl. Chem., 38 (1976) 161.

    Google Scholar 

  22. G. D. Klinskii D. A. Knyazev G. I. Vlasova, Russ. J. Phys. Chem., 48 (1974) 380.

    Google Scholar 

  23. T. Oi H. Ogino M. Hosoe H. Kakihana, Separ. Sci. Technol., 27 (1992) 631.

    Google Scholar 

  24. A. Kondoh T. Oi M. Hosoe, Separ. Sci. Technol., 31 (1996) 39.

    Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Physical Chemistry Laboratory, College of Natural Sciences, Chungbuk National University, Cheongju, 361-763, Republic of Korea

    D. W. Kim, B. M. Kang & B. K. Jeon

  2. Division of Chemical Analysis, Korea Atomic Energy Research Institute, Daejeon, 305-606, Republic of Korea

    Y. S. Jeon

Authors
  1. D. W. Kim
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  2. B. M. Kang
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  3. B. K. Jeon
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  4. Y. S. Jeon
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Kim, D.W., Kang, B.M., Jeon, B.K. et al. Separation of lithium isotopes by elution chromatography with an AB18C6 bonded Merrifield peptide resin. Journal of Radioanalytical and Nuclear Chemistry 256, 81–85 (2003). https://doi.org/10.1023/A:1023352126261

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  • DOI: https://doi.org/10.1023/A:1023352126261

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