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Reactions of Phenylenedioxytrihalophosphoranes with Arylacetylenes: IV.1 Features of the Reaction of 2,2,2,4,5,6,7-Heptachlorobenzo[d]-1,3,2λ5-dioxaphosphole with Phenylacetylene. Molecular and Supramolecular Structure of 2-Oxo-4-phenyl-2,5,6,7,8-pentachlorobenzo[e]-1,2λ5(2H)-oxaphosphorine and Its Hydrolysis Products

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Abstract

As shown by NMR and IR spectroscopy and high-resolution mass spectrometry, the major products of the reaction of 2,2,2,4,5,6,7-heptachlorobenzo[d]-1,3,2λ5-dioxaphosphole with phenylacetylene are a six-membered heterocyclic compound, 2-oxo-4-phenyl-2,5,6,7,8-pentachlorobenzo[e]-1,2λ5(2H)-oxaphosphorine, and the E and Z isomers of 2-(2,3,4,4,5-pentachlorocyclohexadienon-6-yl)-2-phenylvinylphosphonic dichloride. The molecular and supramolecular structure of the heterocycle and phosphorus-containing products of its hydrolysis were studied by single crystal X-ray diffraction.

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Authors and Affiliations

  1. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Tatarstan, Russia

    V. F. Mironov, A. T. Gubaidullin, A. A. Shtyrlina, I. A. Litvinov, R. R. Petrov, A. I. Konovalov', A. B. Dobrynin, T. A. Zyablikova, R. Z. Musin & V. I. Morozov

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  2. A. T. Gubaidullin
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Mironov, V.F., Gubaidullin, A.T., Shtyrlina, A.A. et al. Reactions of Phenylenedioxytrihalophosphoranes with Arylacetylenes: IV.1 Features of the Reaction of 2,2,2,4,5,6,7-Heptachlorobenzo[d]-1,3,2λ5-dioxaphosphole with Phenylacetylene. Molecular and Supramolecular Structure of 2-Oxo-4-phenyl-2,5,6,7,8-pentachlorobenzo[e]-1,2λ5(2H)-oxaphosphorine and Its Hydrolysis Products. Russian Journal of General Chemistry 72, 1764–1783 (2002). https://doi.org/10.1023/A:1023349414864

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