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Synthesis and Properties of Copper(II) Tetra(2-alkyl-4,5-benzimidazolo)- and Tetra(2,2'-Dimethyl-4,5-benzodiazepino)porphyrazines

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Abstract

4,5-Diaminophthalonitrile was reacted with carboxylic acids and acetylacetone to synthesize 2-alkyl-5,6-dicyanobenzimidazoles and 2,2'-dimethyl-5,6-dicyanobenzodiazepine, respectively. The products were converted into copper(II) porphyrazines. An effect of the heterocyclic residue on the physicochemical and spectral properties of the porphyrazines was revealed.

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Authors and Affiliations

  1. Ivanovo State University of Chemical Engineering, Ivanovo, Russia

    A. E. Balakirev, E. V. Kudrik & G. P. Shaposhnikov

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  1. A. E. Balakirev
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  2. E. V. Kudrik
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  3. G. P. Shaposhnikov
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Balakirev, A.E., Kudrik, E.V. & Shaposhnikov, G.P. Synthesis and Properties of Copper(II) Tetra(2-alkyl-4,5-benzimidazolo)- and Tetra(2,2'-Dimethyl-4,5-benzodiazepino)porphyrazines. Russian Journal of General Chemistry 72, 1616–1619 (2002). https://doi.org/10.1023/A:1023343918982

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  • DOI: https://doi.org/10.1023/A:1023343918982

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