Abstract
Electric fluctuation and noise accompany all electrode processes and can be employed for creating useful information technologies. Severe nonlinearity of electrochemical systems gives rise to a perceptible component of abnormal (non-Gaussian) electric noise. In this paper a fluctuation–dissipation theorem is formulated, which connects third-order noise spectra with faradaic low-level rectification. An analogue is provided: the Schottky formulas for the spectrum of third-order shot noise.
Similar content being viewed by others
References
Marcus, R.A., J. Chem. Phys., 1956, vol. 24, p. 966.
Dogonadze, R.R., in Reactions of Molecules at Electrodes, Hush, N.S., Ed., London: Wiley Interscience, 1971, p. 135.
Marcus, R.A., J. Electroanal. Chem., vol. 483, p. 2.
Nyquist, H., Phys. Rev., 1928, vol. 32, p. 97.
Callen, H.B. and Welton, N.A., Phys. Rev., 1951, vol. 83, p. 34.
Callen, H.B. and Greene, R.F., Phys. Rev., 1952, vol. 86, p. 702.
Khaus, G. and Adler, R., Teoriya lineinykh shumyashchikh tsepei (Theory of Linear Noise-Generating Circuits), Moscow: Izdatel'stvo Inostrannoi Literatury, 1963.
Malakhov, A.I., Kumulyantnyi analiz sluchainykh negaussovskikh protsessov i ikh preobrazovanii (A Cumulant Analysis of Random Non-Gaussian Processes and Their Transforms), Moscow: Sovetskoe Radio, 1978.
Brillinger, D.R., Ann. Math. Statistics, 1965, vol. 36, p. 1351.
Dawson, J.L., Proc. First Int. Symp. Electrochem. Noise Measurement for Corrosion Applications, Montreal: West Conshohecken, 1996, p. 3.
Bernard, W. and Callen, H.B., Reviews of Modern Physics, 1959, vol. 31, p. 1017.
Kampen, N.G., J. Math. Phys., 1962, vol. 4, p. 190.
Efremov, G.F., Zh. Exp. Teor. Fiz., 1968, vol. 54, p. 2322.
Bochkov, G.N. and Kuzovlev, Yu.E., Zh. Exp. Teor. Fiz., 1977, vol. 72, p. 238.
Stratonovich, R.L., Nelineinaya neravnovesnaya termodinamika (Nonlinear Nonequilibrium Thermodynamics), Moscow: Nauka, 1985, p. 114.
Weiss, L. and Mathis, W., Int. J. Circ. Theor. Appl, 1998, vol. 26, p. 147.
Stoynov, Z.B., Grafov, B.M., Savova-Stoynova, B.S., and Elkin, V.V., Elektrokhimicheskii impedans (The Electrochemical Impedance), Moscow: Nauka, 1991, p. 262.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Grafov, B.M. Fluctuation–Dissipation Theorem for Triple Correlations of Electric Noise. Russian Journal of Electrochemistry 39, 423–426 (2003). https://doi.org/10.1023/A:1023326509725
Issue Date:
DOI: https://doi.org/10.1023/A:1023326509725