Abstract
The electroconductivity of molten mixtures of calcium, strontium, and barium chlorides with potassium chloride (component concentrations 0, 25, 50, 75, 100 mol %) is studied as a function of the electric field strength. Isotherms of extreme high-voltage conductivities of the mixtures are an additive function of the composition, as opposed to isotherms of low-voltage conductivity, which exhibit considerable deviations and pass through minimums.
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Diller, J.M., Nature (London), 1969, vol. 224, p. 877.
Shabanov, O.M., Fizicheskaya khimiya ionnykh rasplavov (Physical Chemisty of Ionic Melts), Sverdlovsk, 1987, vol. 1, p. 64.
Gadzhiev, S.M., Guseinov, R.M., Gebekova, Z.G., and Gadzhiev, A.S., Elektrokhimiya, 1998, vol. 34, p. 106.
Shabanov, O.M., Gadzhiev, S.M., Magomedova, A.O., and Gadzhiev, A.S., Vestn. Dagestan. Gos. Un-ta: Estestv. Nauki, 1999, no. 1, p. 119.
Shabanov, O.M. and Gadzhiev, S.M., Rasplavy, 1990, no. 2, p. 49.
Shabanov, O.M., Rasplavy, 1987, vol. 1, no. 5, p. 66.
Gadzhiev, S.M. and Prisyazhnyi, V.D., Ionnye rasplavy i tverdye elektrolity (Ionic Melts and Solid Electrolytes), Kiev: Naukova Dumka, 1986, p. 21.
Smirnov, M.V., Shabanov, O.M., and Khaimenov, A.P., Elektrokhimiya, 1966, vol. 2, p. 1240.
Kirillov, S.A., Fizicheskaya khimiya i elektrokhimiya rasplavlennykh solei (Physical Chemistry and Electrochemistry of Malten Salts), Nal'chik, 2001, vol. 1, p. 31.
Markov, B.F. and Delimarskii, Yu.K., Ukr. Khim. Zh., 1953, vol. 19, p. 255.
Stepanov, V.P. and Smirnov, M.V., Rasplavy, 1987, vol. 1, p. 76.
Trifonov, I.I., Rasplavy, 1993, no. 2, p. 47.
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Gadzhiev, S.M., Shabanov, O.M., Magomedova, A.O. et al. Extreme High-Voltage Electroconductivity of Molten KCl–MCl2 (M = Ca, Sr, Ba). Russian Journal of Electrochemistry 39, 386–390 (2003). https://doi.org/10.1023/A:1023310006090
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DOI: https://doi.org/10.1023/A:1023310006090