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Effect of a Competing n Donor on the Rate of AlCl3-Catalyzed Diels-Alder Reaction of 9,10-Dimethylanthracene with Maleic Anhydride

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Abstract

The catalytic effect of AlCl3 on the Diels-Alder reaction of 9,10-dimethylanthracene with maleic anhydride is dramatically weakened on addition of a competing n donor, dibutyl ether. The n,v complex of aluminum chloride with dibutyl ether is considerably more stable than the complex with maleic anhydride; therefore, the catalytic effect is suppressed even at comparable concentrations of these n donors.

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Authors and Affiliations

  1. Butlerov Research Chemical Institute, Kazan State University, Kazan, Tatarstan, Russia

    V. D. Kiselev, E. A. Kashaeva & A. I. Konovalov

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  1. V. D. Kiselev
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  2. E. A. Kashaeva
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  3. A. I. Konovalov
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Kiselev, V.D., Kashaeva, E.A. & Konovalov, A.I. Effect of a Competing n Donor on the Rate of AlCl3-Catalyzed Diels-Alder Reaction of 9,10-Dimethylanthracene with Maleic Anhydride. Russian Journal of General Chemistry 72, 1793–1796 (2002). https://doi.org/10.1023/A:1023305732611

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