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Synthesis and X-ray structure of N-phenyl phenylglyoxamide

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Abstract

The title compound (C14H11NO2) is monoclinic with a = 13.579(2), b = 5.297(1), c = 16.455(2) Å, β = 98.11(2)°, Z = 4, and space group P21/n. The significant structural features lie in the two carbonyl groups of the glyoxamide which are oriented antiperiplanar to each other [−163.6(3)°]. The central bond C(1)–C(2) is 1.545(4) Å. The observed conformation is stabilized by intramolecular hydrogen bonds.

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Authors and Affiliations

  1. Department of Organic Chemistry, Silesian School of Medicine, 4 Jagiellońska Str., 41-200, Sosnowiec, Poland

    Stanisław Boryczka

  2. Institute of Physical Chemistry, Polish Academy of Sciences, 01-224, Warszawa, Poland

    Kinga Suwińska

  3. Laboratoire d'Electrochimie Organique UA CNRS 439, Universite Catholique de l'Ouest, BP 808, 49008, Angers Cedex 01, France

    Georges Le Guillanton, Quang Tho Do & Driss Elothmani

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  1. Stanisław Boryczka
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  2. Kinga Suwińska
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  3. Georges Le Guillanton
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  4. Quang Tho Do
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  5. Driss Elothmani
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Boryczka, S., Suwińska, K., Le Guillanton, G. et al. Synthesis and X-ray structure of N-phenyl phenylglyoxamide. Journal of Chemical Crystallography 28, 555–560 (1998). https://doi.org/10.1023/A:1023248223359

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