Skip to main content
Log in

Modification of the Photochemical Reactions of Protein Tryptophanyls by Chloroform

  • Published:
Journal of Applied Spectroscopy Aims and scope

Abstract

The modifying action of chloroform and other halogenmethanes (difluorodichloromethane and carbon tetrachloride) on UV radiation-induced photochemical reactions of the protein tryptophanyls is shown. The effect manifests itself in an increase in the quantum yield of indole chromophore destruction and in formation of new photochemical products. It is found that the nature of the products of photochemical destruction which are formed in a tryptophan solution and in proteins is the same.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

REFERENCES

  1. S. V. Konev and I. D. Volotovskii, Photobiology [in Russian], Minsk (1979).

  2. S. V. Konev and I. D. Volotovskii, in: Photobiology of Animal Cells [in Russian], Leningrad (1979), pp. 5–16.

  3. I. E. Kochevar, Photochem. Photobiol., 52, 795–800 (1990).

    Google Scholar 

  4. A. V. Vorobei, E. A. Chernitskii, S. V. Konev, A. P. Krivitskii, S. V. Pinchuk, and N. A. Shukanova, Biofizika, 37, 848–850 (1992).

    Google Scholar 

  5. S. V. Pinchuk and A. V. Vorobei, Zh. Prikl. Spektrosk., 59, 312–317 (1993).

    Google Scholar 

  6. A. V. Vorobei, S. V. Pinchuk, and N. A. Shukanova, Dokl. Akad. Nauk Belarusi, 36, 562–564 (1992).

    Google Scholar 

  7. J. S. Reif, M. C. Hatch, and M. Bracken, Environ. Health Perspect., 104, 1056–1061 (1996).

    Google Scholar 

  8. Yu. A. Vladimirov, Photochemistry and Luminescence of Proteins [in Russian], Moscow (1965).

  9. J. D. Tassin and R. F. Borkman, Photochem. Photobiol., 32, 577–585 (1981).

    Google Scholar 

  10. L. B. Hibbard, N. J. Kirk, and R. F. Borkman, Photochem. Photobiol., 42, 99–106 (1985).

    Google Scholar 

  11. J. Dillon, Photochem. Photobiol., 33, 137–142 (1981).

    Google Scholar 

  12. I. D. Volotovskii, Study of Primary Photophysical Processes in the Tryptophan of Proteins, Candidate’s Dissertation (in Biology), Minsk (1967).

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Pinchuk, S.V., Vorobei, A.V. Modification of the Photochemical Reactions of Protein Tryptophanyls by Chloroform. Journal of Applied Spectroscopy 70, 54–58 (2003). https://doi.org/10.1023/A:1023216307500

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1023216307500

Navigation