Abstract
The layered double hydroxide (LDH) well known for its abilityto intercalate anionic compounds has been prepared conventionallyonly with bivalent and trivalent cations. In this study, Zn–Ti LDH consisting of bivalent and tetravalent cations was prepared, andreacted with organic monocarboxylic, dicarboxylic and aromatic acidsat high or room temperature. XRD patterns of the prepared LDH(Zn–Ti-CO3) showed that interlayer spacing of the LDH was 0.67 nm. The value was small compared to the usual LDH (Zn–Al–CO3)of 0.76 nm in the case of carbonate anion as the guest. Also, DTA,TG and DTG analysis indicated that the electrostatic force betweenthe layers and carbonate anions increased where the carbonate anionsin Zn–Ti LDH decomposed at 255 °C while those inZn–Al–CO3 decomposed at 230–240 °C.
Similar content being viewed by others
References
F. Cavani, F. Trifiro and A. Vaccari: Catal. Today 11, 173 (1991).
S.P. Newman and W. Jones: New J. Chem. 22, 105 (1998).
T. Takatsuka, H. Kawasaki, S. Yamashita and S. Kohjiya: Bull. Chem. Soc. Jpn. 52, 2449 (1979).
S. Kohjiya, T. Sato, T. Nakayama and S. Yamashita: Macromol. Rapid Commun. 2, 231 (1981).
W.T. Reichle: J. Catal. 94, 547 (1985).
E. Suzuki and Y. Ono: Bull. Chem. Soc. Jpn. 61, 1008 (1988).
H. Schaper, J.J. Berg-Slot and W.H.J. Stork: Appl. Catal. 54, 79(1989).
L. Barloy, J. P. Lallier, P. Battioni, D. Mansuy, Y. Piffard, M. Tournoux, J. B. Valim and W. Jones: New J. Chem. 16, 71 (1992).
P.C. Pavan, G.D. Gomes and J.B. Valim: Microporous Mesoporous Mater. 21, 659 (1998).
P.C. Pavan, E.L. Crepaldi, G.D. Gomes and J.B. Valim: Colloids Surf. A 154, 399 (1999).
S. Miyata and T. Kumura: Chem. Lett. 843 (1973).
M. Meyn, K. Beneke and G. Lagaly: Inorg. Chem. 29, 5201 (1990).
A. Schmassmann, A. Tarnawski, B. Flogerzi, M. Sanner, L. Varga and F. Halter: Eur. J. Gastroenterol. Hepatol. 5, S111 (1993).
J. Choy, S. Kwak, J. Park, Y. Jeong and J. Portier: J. Am. Chem. Soc. 121, 1399 (1999).
A. Fogg, V. Green, H. Harvey and D. O'Hare: Adv. Mater. 11, 1466 (1999).
H. Tagaya, S. Ogata, S. Nakano, J. Kadokawa, M. Karasu and K. Chiba: J. Inclusion Phenomena 31, 231 (1998).
S. Ogata, H. Tagaya, M. Karasu, J. Kadokawa and K. Chiba: Trans. MRS-J. 24, 501 (1999).
S. Ogata, H. Tagaya, M. Karasu and J. Kadokawa: J.Mater. Chem. 10, 321 (2000).
T. Takahashi, H. Adachi, J. Kadokawa and H. Tagaya: Trans. Mater Res. Soc. Jpn. 26(2), 491 (2001).
H. Tagaya, S. Sato, T. Kuwahara, J. Kadokawa, M. Karasu and K. Chiba: J. Mater. Chem. 4, 1907 (1994).
H. Tagaya, A. Ogata, T. Kuwahara, S. Ogata, M. Karasu, J. Kadokawa and K. Chiba: Microporous Materials 7, 151 (1996).
H. Tagaya and S. Ogata: Function and Material 18, 33 (1998).
Shimadzu ESCA Data: ESCA 750.
A. Roy, C. Forano, K. Elmalki and J. Besse: in M. L. Occelli and H. Robson (eds.), Expanded Clay and other Microporous Solids, Synthesis of Microporous Materials, V. Reinhold, New York, Ch. 7, p. 108 (1992).
V. Rives and S. Kannan: J. Mater. Chem. 10, 489 (2000).
M.C. Gastuche, G. Brown and M. Mortland, Clay Minerals 7, 72 (1967).
C. Busetto, G. Del Piero, and G. Manara: J. Catal. 85, 260 (1984).
R. Allmam and H.H. Lohse: N. Jhb. Miner. Mh. 6, 161 (1966).
F. Leroux, M. Adachi-Pagano, M. Intissar, S. Chauviere, C. Forano and J. Besse: J. Mater. Chem. 11, 105 (2001).
JCPDS file No. 20-1437.
Constantino and T. Pinnavaia: Inorg. Chem. 34(4), 883 (1995).
S. Yun and T. Pinnavaia: Chem. Mater. 7, 348 (1995).
A. Vaccari: Appl. Clay Sci. 14, 161 (1999).
F.M. Labajos, V. Rives and M.A. Ulibarri: J. Mater. Sci. 27, 1546 (1992).
S. Miyata: Clays Clay Miner. 23, 369 (1995).
E.C. Kruissink, L.L. Van Reijden and J.R.H. Ross: J. Chem. Soc., Faraday Trans. 1 77, 649 (1991).
J. Perez-Ramirez, G. Mul, F. Kapteijn and J.A. Moulijn: J. Mater. Chem. 11, 821 (2001).
N. Nakamoto: Infrared and Raman Spectra of Inorganic and Coordination Compounds, 4th edn., John Wiley &; Sons, New York (1986).
M.K. Titulaer, J.B.H. Jansen and J.W. Geus: Clays Clay Miner. 42, 249 (1994).
T. Kanoh, T. Shichi and K. Takagi: Chem. Lett. 117 (1999).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Saber, O., Tagaya, H. New Layered Double Hydroxide, Zn–Ti LDH : Preparation and Intercalation Reactions. Journal of Inclusion Phenomena 45, 107–115 (2003). https://doi.org/10.1023/A:1023078728942
Issue Date:
DOI: https://doi.org/10.1023/A:1023078728942