Capture and Controlled Release of Fragrances by CD Finished Textiles

Abstract

Cotton, wool and polyester fabrics finished with cyclodextrins (by the intermediateof polycarboxylic acids) were impregnated with six different fragrant molecules(β-citronellol, camphor, menthol, cis-jasmone, benzyl acetate, geraniol) and citronella oil. The smell intensity of the samples has been investigated during almostone year. In most cases, the odour retention of untreated textiles towards the substratesdid not persist over one or two weeks. By contrast, most of the treated sampleskept smelling one year after the beginning of the experiment. We observed that theuse of polyacrylic acid as crosslinking agent was less effective than citric andbutanetetracarboxylic acids. The efficiency of the different CDs varied in the orderγ-CD > β-CD > α-CD, and the durability of the fragranteffect was directly dependent on the amount of CD grafted onto the fabrics.