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Raman Spectroscopy of Iron in Aqueous Carbonate Solutions

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Abstract

Surface-enhanced Raman spectroscopy is used for in situ study of an iron surface in aqueous carbonate solutions both on open circuit and at constant potentials. Raman signals are assigned to FeCO3 and adsorbed water. Formation of FeCO3 corresponds to lowering of iron dissolution.

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Authors and Affiliations

  1. Department of Chemistry, University of Louisiana, Lafayette, Louisiana, 70504

    Richard S. Perkins

  2. Department of Chemical Engineering, University of Louisiana, Lafayette, Louisiana, 70504

    James D. Garber

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  1. Richard S. Perkins
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  2. James D. Garber
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Perkins, R.S., Garber, J.D. Raman Spectroscopy of Iron in Aqueous Carbonate Solutions. Journal of Solution Chemistry 32, 265–272 (2003). https://doi.org/10.1023/A:1022990402530

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