Skip to main content
SpringerLink
Log in

Hydrothermal Syntheses and Structural Characterization of One-Dimensional [Cu4Br2I3(C12H8N2)2] n and Molecular Cu3Br3(C12H8N2)2

  • Published:
Journal of Cluster Science Aims and scope Submit manuscript

Abstract

The hydrothermal reactions of CuBr2, CuX (X=Br, I), and phen (phen=1,10-phenanthroline, C12H8N2) have lead to the syntheses of two novel complexes of one-dimensional [Cu4Br2I3(phen)2] n 1 and trinuclear discrete cluster Cu3Br3(phen)2 2. Both compounds were characterized by singe-crystal X-ray diffraction. Crystal data for 1. Monoclinic, space group P2 1/c with a=14.054(3) Å, b=13.700(3) Å, c=15.920(3) Å, β=114.16(3)°, Z=2; 2. Monoclinic, space group C2/c with a=10.040(2) Å, b=14.516(3) Å, c=16.319(3) Å, β=94.29(3)°, Z=6.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. M. Rodríguez, A. Llobet, M. Corbella, A. E. Martell, and J. Reibenspies (1999). Inorg. Chem. 38, 2328.

    Google Scholar 

  2. C. Diaz, J. Ribas, N. Sanz, X. Solans, and M. Font-Bardia (1999). Inorg. Chim. Acta. 286, 169.

    Google Scholar 

  3. Megumu Munakata, Shigwru Nishibayashi, and Hiromasa Sakamoto (1980). J. C. S. Chem. Commun. 219.

  4. N. P. Rath, E. M. Holt, and K. Tanimura (1986). J. Chem. Soc. Dalton. 2303.

  5. N. P. Rath, E. M. Holt, and K. Tanimura (1985). Inorg. Chem. 24, 3934.

    Google Scholar 

  6. A. J. Pallenberg, K. S. Koening, and D. M. Barnhart (1995). Inorg. Chem. 34, 2833.

    Google Scholar 

  7. H. Place, B. Scott, G. S. Long, and R. D. Willett (1998). Inorg. Chim. Acta. 279, 1.

    Google Scholar 

  8. H. Place, B. Scott, G. S. Long, and R. D. Willett (1998). Inorg. Chim. Acta. 319, 43.

    Google Scholar 

  9. J. Y. Lu, B. R. Cabrera, R.-J. Wang, and J. Li (1998). Inorg. Chem. 37, 4480.

    Google Scholar 

  10. P. C. Healy, C. Pakawatchai, C. L. Raston, B. W. Skelton, and A. H. White (1983). J. Chem. Soc. Dalton. 1905.

  11. N. P. Rath, J. L. Maxwell, and E. M. Holt (1986). J. Chem. Soc. Dalton. 2449.

  12. C. B. Aakeröy, A. M. Beatty, and K. R. Lorimer (2000). J. Chem. Soc. Dalton. 3869.

  13. G.-Z. Hu, and E. M. Holt (1994). Acta Cryst. C 50, 1578.

    Google Scholar 

  14. P. M. Graham, R. D. Pike, M. Sabat, R. D. Bailey, and W. T. Pennington (2000). Inorg. Chem. 39, 5121.

    Google Scholar 

  15. A. J. Blake, N. R. Brooks, N. R. Champness, P. A. Cooke, A. M. Deveson, D. Fenske, P. Hubberstey, W.-S. Li, and M. Schröder (1999). J. Chem. Soc. Dalton. 2103.

  16. N. Masciocchi, P. Cairati, L. Carlucci, G. Mezza, G. Ciani, and A. Sironi (1996). J. Chem. Soc. Dalton. 2739.

  17. J. Y. Lu, B. R. Cabrera, R.-J. Wang, and J. Li (1999). Inorg. Chem. 38, 4608.

    Google Scholar 

  18. J. M. Moreno, J. Suarez-Varela, E. Colacio, J. C. Avila-Rosón, M. A. Hidalgo, and D. Martin-Ramos (1995). Can. J. Chem. 73, 1591.

    Google Scholar 

  19. R. Kuhlman, G. L. Schimek, and J. W. Kolis (1999). Polyhedron 18, 1379.

    Google Scholar 

  20. R. P. Hammond, M. Cavaluzzi, R. C. Haushalter, and J. A. Zubieta (1999). Inorg. Chem. 38, 1288.

    Google Scholar 

  21. B. Freckmann and K.-F. Tebbe (1980). Z. Natureforce. Teil. B 35, 1319.

    Google Scholar 

  22. J. R. D. DeBord, Y.-J. Lu, C. J. Warren, R. C. Haushalter, and J. Zubieta (1997). Chem. Commun. 1365.

  23. J.-H. Yu, Z. Shi, J.-Q. Xu, D.-Q. Chu, W.-J. Jing, H. Ding, J. Hua, J.-N. Xu, X.-B. Cui, T.-G. Wang, L.-J. Zhang, C.-B. Li, and Q.-X. Zeng (2001). Polish J. Chem. 75, 1785.

    Google Scholar 

  24. SHELXTL, version 5.1; Siemens. Industrial Automation (1997).

  25. G. Nardin, L. Randaccio, and E. Zangrando (1775). J. Chem. Soc. Dalton. 2566.

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun Jinlin, 130023, People's Republic of China

    Jie-Hui Yu, Ji-Qing Xu, Hong Ding, Jia-Ning Xu & Tie-Gang Wang

  2. Key Laboratory of Supramolecular structure and Materials of Ministry of Education, Jilin University, Changchun Jinlin, 130023, People's Republic of China

    Ling Ye, Zhong-Cheng Mu & Guang-Di Yang

  3. Department of Chemistry, Inner Mongolia University for Nationalities, People's Republic of China

    Hong-Bin Jia

Authors
  1. Jie-Hui Yu
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Ji-Qing Xu
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Ling Ye
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Hong Ding
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Jia-Ning Xu
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Hong-Bin Jia
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Tie-Gang Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. Zhong-Cheng Mu
    View author publications

    You can also search for this author in PubMed Google Scholar

  9. Guang-Di Yang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Ji-Qing Xu.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Yu, JH., Xu, JQ., Ye, L. et al. Hydrothermal Syntheses and Structural Characterization of One-Dimensional [Cu4Br2I3(C12H8N2)2] n and Molecular Cu3Br3(C12H8N2)2 . Journal of Cluster Science 14, 1–8 (2003). https://doi.org/10.1023/A:1022953222576

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1022953222576

Search

Navigation