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A Comparative Study of the Effect of Air Plasma and Ozone on the Poly(methylphenylvinylsiloxane) Rubber SKTFV-803

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Abstract

The depths of crosslink propagation and ozone penetration resulting from the exposure of the SKTFV-803 rubber to a gas-discharge plasma and ozone–oxygen mixture were measured. The propagation of crosslinking to a depth of up to 30 μm initiated by air plasma (pressure 13 Pa, average specific energy consumption of J = 0.01 W/cm3) is interpreted as the result of interaction with ozone; it is assumed that a steady-state ozone concentration at the surface and in near-surface layers of rubber specimens during discharge treatment considerably exceeds the equilibrium concentration in the gas phase.

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Tikhomirov, L.A. A Comparative Study of the Effect of Air Plasma and Ozone on the Poly(methylphenylvinylsiloxane) Rubber SKTFV-803. High Energy Chemistry 37, 111–114 (2003). https://doi.org/10.1023/A:1022892500965

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