Abstract
Two independent methods, the isotope method based on nuclear microanalysis and the method based on measuring the electronic-conductivity activation energy, are used to determine the grain-boundary diffusion and volume diffusion of an oxygen isotope 18O in a polycrystalline lithium-titanium ferrite at the thermal annealing temperature 1073 K. A comparative analysis is conducted of the potential of the methods in studying oxygen diffusion in the material concerned. It is shown that the technique for obtaining the diffusion parameters from the electronic conductivity measurements allows a comparatively precise determination of both the volume and grain-boundary diffusion coefficients of oxygen in polycrystalline ferrites.
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REFERENCES
G. B. Fedorov and E. A. Smirnov, Diffusion in Reactor Materials [in Russian], Moscow, Atomizdat (1978).
G. Amsel, D. David, G. Beranger, and P. Boist, Rev. Phys. Appl., 3, No. 3 (1968) P. 873-893.
F. Millot, C. Picard, and J. Berthon, High Temperatures-High Pressures, 19, 337-342 (1987).
B. E. Levin, Yu. D. Tretyakov, and L. M. Letyuk, Physicochemical Principles of Production of Ferrites, their Properties and Application [in Russian], Metallurgiya, Moscow (1979).
M. T. Varshavskii, V. P. Pashchenko, A. N. Men', et al., Nauka, Moscow (1982).
A. P. Surzhikov, V. V. Peshev, A. M. Pritulov, and S. A. Ghyngazov, Russ. Phys. J., No. 5, 490 (1999).
D. David, G. Berenger, and E. A. Garcia, J. Electr. Chem. Soc., 130, No. 6, 1426-1429 (1983).
V. B. Vykhodets, S. M. Klotsman, T. E. Kurennykh, et al., Fiz. Met. Metalloved., 63, No. 5, 974-981 (1987).
V. B. Vykhodets, S. M. Klotsman, and B. E. Levin, Fiz. Met. Metalloved., 64, No. 5, 920-924 (1987).
V. B. Vykhodets, T. E. Kurennykh, G. A. Kozhina, et al. Oxides: Physicochemical Properties and Production Technologies [in Russian], Proc. Sci. Pract. Conf., Ekaterinburg, Ural Akad. Nauk (1998).
A. P. Surzhikov, A. M. Pritulov, S. A. Ghyngazov, and E. N. Lysenko, Promising Materials [in Russian], No. 6, 90-94 (1999).
Russian Patent No 2169914, A method for Determining Diffusion Constants in Polycristalline Solids (A. P. Surzhikov, A. M. Pritulov, S. A. Ghyngazov, and E. N. Lysenko).
R. T. F. Whipple, Phil. Mag., 45, 1225-1236 (1954).
I. Kaur and V. Gust, Fundamentals of Grain and Interphase Boundary Diffusion, Ziegler Press, Stuttgart (1989).
A. P. Surzhikov, A. P. Peshev, S. A. Ghyngazov, and E. N. Lysenko, Promising Materials, Technologies, and Structures — Economic aspects, Collected Scientific Papers (ed. V. V. Statsura) [in Russian], Krasnoyarsk, SACMU No. 6, 59-62 (2000).
L. P. Pavlov, Methods of Measuring Parameters of Semiconductor Materials [in Russian] Vyssh. Shkola., Moscow (1987).
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Surzikov, A.P., Lysenko, E.N., Ghyngazov, S.A. et al. Determination of the Oxygen Diffusion Coeficient in Polycrystalline Li-Ti Ferrites. Russian Physics Journal 45, 989–996 (2002). https://doi.org/10.1023/A:1022862900424
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DOI: https://doi.org/10.1023/A:1022862900424