Abstract
The plasmochemical and/or electrocatalytical reactions of carbon monoxide with water vapour were studied. Dc corona discharge of both polarities at room temperature and temperatures enhanced up to 70°C was applied at pressures close to atmospheric.
The reaction products were analysed by IR absorption spectrometry. The main products in the gas phase were CO2 and CH4. The reactions are influenced by the formation of a catalytically active surface layer on electrodes. The composition of this layer depends on the polarity of electrode.
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Morvová, M. The influence of water vapour and temperature on depletion of carbon monoxide in D.C. corona discharge. Czech J Phys 49, 1703–1719 (1999). https://doi.org/10.1023/A:1022832003737
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DOI: https://doi.org/10.1023/A:1022832003737