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Internal Mobility, Phase Transition, and Ionic Conductivity in Thallium(I) Heptafluorodiantimonate(III)

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Abstract

The internal mobility of fluorine ions and the electrophysical properties of TlSb2F7 were studied by the 19F NMR method and impedance spectroscopy. Modes of ionic motions in the fluoride subsystem were determined in the temperature range 213–430 K. A structural phase transition is found to occur at 400 K, resulting in the β‐TlSb2F7 modification characterized by high ionic (superionic) conductivity in the temperature range of 400–430 K σ∼ 2.5·10-3 S/cm at 430 K).

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REFERENCES

  1. S. H. Mastin and R. R. Ryan, Inorg. Chem., 10, No. 8, 1757-1760 (1971).

    Google Scholar 

  2. D. Tichit, B. Ducourant, R. Fourcade, and G. Mascherpa, J. Fluor. Chem., 13, No. 1, 45-53 (1979).

    Google Scholar 

  3. R. R. Ryan, S. H. Mastin, and A. C. Larson, Inorg. Chem., 10, No. 12, 2793-2795 (1971).

    Google Scholar 

  4. A. A. Udovenko, Yu. E. Gorbunova, R. L. Davidovich, et al., Koord. Khim., 26, No. 9, 662-665 (2000).

    Google Scholar 

  5. N. Habibi, B. Ducourant, R. Fourcade, and G. Mascherpa, Bull. Soc. Chim. France, No. 11, 2320-2324 (1974).

    Google Scholar 

  6. R. L. Davidovich and L. A. Zemnukhova, Koord. Khim., 1, No. 4, 477-481 (1975).

    Google Scholar 

  7. M. P. Borzenkova, F. V. Kalinichenko, A. V. Novoselova, et al., Zh. Neorg. Khim., 29, No. 3, 703-705 (1984).

    Google Scholar 

  8. V. V. Fomichev, K. I. Petrov, L. A. Sadokhina, et al., Koord. Khim., 2, No. 1, 77-82 (1976).

    Google Scholar 

  9. Yu. Ya. Kharitonov, R. L. Davidovich, V. I. Kostin, et al., Zh. Neorg. Khim., 27, No. 5, 1316-1324 (1972).

    Google Scholar 

  10. T. Birchall and B. Della Valle, Canad. J. Chem., 49, No. 17, 2808-2812 (1971).

    Google Scholar 

  11. É. A. Kravcheko, R. L. Davidovich, L. A. Zemnukhova, and Yu. A. Buslayev, Dokl. Akad. Nauk SSSR, 214, No. 3, 611-614 (1974).

    Google Scholar 

  12. L. A. Zemnukhova and R. L. Davidovich, Izv. Akad. Nauk SSSR, Ser. Fiz., 45, No. 9, 1764-1767 (1981).

    Google Scholar 

  13. L. A. Zemnukhova and R. L. Davidovich, Z. Naturforsch., 53a, 573-584 (1998).

    Google Scholar 

  14. V. Ya. Kavun, V. I. Sergienko, N. I. Sorokin, et al., Zh. Strukt. Khim., 42, No. 4, 685-694 (2001).

    Google Scholar 

  15. V. Ya. Kavun, V. I. Sergienko, N. I. Sorokin, et al., Zh. Strukt. Khim., 42, No. 5, 917-920 (2001).

    Google Scholar 

  16. Yu. Ya. Gurevich and Yu. I. Kharkatz, Superionic Conductors [in Russian], Nauka, Moscow (1992).

    Google Scholar 

  17. V. M. Buznik, V. A. Vopilov, A. I. Livshits, and V. N. Voronov, “Nuclear magnetic resonance in solid electrolytes,” Preprint No. 157F, Inst. of Physics, Sib. Branch, USSR Acad. of Sci., Krasnoyarsk (1981).

  18. J. S. Waugh, and É. I. Fedin, Fiz. Tverd. Tela, 4, No. 8, 2233-2237 (1962).

    Google Scholar 

  19. A. Abragam, The Principles of Nuclear Magnetism, Oxford (1961).

  20. A. A. Udovenko, L. M. Volkova, Koord. Khim., 7, No. 12, 1763-1813 (1981).

    Google Scholar 

  21. S. P. Gabuda and R. N. Pletnev, NMR Applications in Solid State Chemistry [in Russian], Izd. Ekaterinburg, Ekaterinburg (1996).

    Google Scholar 

  22. Yu. N. Moskvich, B. I. Cherkasov, A. M. Polyakov, et al., Phys. Stat. Solidi (B), 156, No. 2, 615-631 (1989).

    Google Scholar 

  23. S. P. Gabuda, R. L. Davidovich, S. G. Kozlova, and N. K. Moroz, Zh. Strukt. Khim., 37, No. 2, 388-390 (1996).

    Google Scholar 

  24. V. Urbonavichus, “Phase transitions in complex uorine compounds of antimony,” Candidate's Dissertation in Phys.-Math. Sci., Vilnus (1985).

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Authors and Affiliations

  1. Institute of Chemistry, Far East Branch, Russian Academy of Sciences, Vladivostok

    V. Ya. Kavun, N. F. Uvarov, L. A. Zemnukhova & A. B. Slobodyuk

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  1. V. Ya. Kavun
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  2. N. F. Uvarov
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  3. L. A. Zemnukhova
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  4. A. B. Slobodyuk
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Kavun, V.Y., Uvarov, N.F., Zemnukhova, L.A. et al. Internal Mobility, Phase Transition, and Ionic Conductivity in Thallium(I) Heptafluorodiantimonate(III). Journal of Structural Chemistry 43, 766–771 (2002). https://doi.org/10.1023/A:1022817022404

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