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Thermodynamics of liquid Fe-Si and Fe-Ge alloys

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Abstract

The enthalpies of mixing of liquid binary Fe-Ge (1765±5 K) and Fe-Si (1750±5 K) alloys were determined using a high-temperature isoperibolic calorimeter. The thermodynamic properties of Fe-Ge melts were also studied by electromotive force method in the temperature range of 1250-1580 K. The comparison of our measurement results with literature data has been performed. The extreme negative values of integral enthalpy of mixing and alternating-sign deviations from Raoult's low for germanium can be explained by the influence of binary clusters formation.

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Authors and Affiliations

  1. Chemical Department, Kyiv National Taras Shevchenko University, 64, Volodymyrska str., 01033, Kyiv, Ukraine

    D. S. Kanibolotsky, O. A. Bieloborodova, N. V. Kotova & V. V. Lisnyak

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  1. D. S. Kanibolotsky
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  2. O. A. Bieloborodova
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  3. N. V. Kotova
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  4. V. V. Lisnyak
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Correspondence to V. V. Lisnyak.

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Kanibolotsky, D.S., Bieloborodova, O.A., Kotova, N.V. et al. Thermodynamics of liquid Fe-Si and Fe-Ge alloys. Journal of Thermal Analysis and Calorimetry 71, 583–591 (2003). https://doi.org/10.1023/A:1022816229045

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