Abstract
The new sesquiterpene lactone 13-hydroxymethylenedeacetyllaurenobiolide was isolated from the aerial part of Tanacetopsis mucronata S. Koval. (Asteraceae). Its structure was established using spectral data and X-ray structure analysis. The germacranolide macrocycle has the chair-chair conformation with the configuration 1D14, 15D5.
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REFERENCES
M. B. Izbosarov, B. Kh. Abduazimov, A. D. Vdovin, E. L. Kristallovich, and M. P. Yuldashev, Khim. Prir. Soedin., 730 (1999).
B. H. Tada and K. Taceda, J. Chem. Soc., Chem. Commun., 1391 (1971).
F. Bohlmann, J. Jakupovic, and A. Schuster, Phytochemistry, 22, 1637 (1983).
F. Bohlmann, S. Zdero, R. M. King. and H. Robinson, Phytochemistry, 19, 115, (1980).
F. Bohlmann, A. Adler, J. Jakupovic, R. M. King, and H. Robinson, Phytochemistry, 21, 1349 (1982).
F. Bohlmann, J. Jakupovic, M. Ahmed, and A. Schuster, Phytochemistry, 22, 1623 (1983).
F. Shafizaden and N. R. Bhadane, Phytochemistry, 12, 857 (1973).
H. Tada and K. Takeda, Chem. Pharm. Bull., 24, 667 (1976).
B. Kh. Abduazimov, A. I. Yunsov, S. A. Khamidkhodzhaev, and G. P. Sidyakin, Khim. Prir. Soedin., 398 (1981).
M. K. Makhmudov, B. Kh. Abduazimov, B. Tashkhodzhaev, and B. T. Ibragimov, Khim. Prir. Soedin., 59 (1988).
F. N. Allen, O. Kennard, D. G. Watson, et al., J. Chem. Soc., Perkin Trans. 2, No. 12, 1 (1987).
SMART V5.051 and SAINT V5.00, Area detector control and integration software, Bruker AXS Inc., Madison, WI 53719, USA (1998).
G. M. Sheldrick, SADABS, Bruker AXS Inc., Madison, WI 53719, USA (1997).
G. M. Sheldrick, SHELXTL-97, V5.10, Bruker AXS Inc., Madison, WI 53719, USA (1997).
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Tashkhodzhaev, B., Abduazimov, B.K., Izbosarov, M.B. et al. 13α-Hydroxymethylenedeacetyllaurenobiolide, a New Germacranolide from Tanacetopsis mucronata . Chemistry of Natural Compounds 38, 557–560 (2002). https://doi.org/10.1023/A:1022682620162
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DOI: https://doi.org/10.1023/A:1022682620162