Abstract
Supported Co3O4 catalysts were prepared via the calcination of Co-containing hydrogarnet, (Ca3-x Co x )Al2(SiO4)3- y (OH)4y , at 400 °C. Such precursors with various extents of substitution were synthesized from the hydrothermal reaction of a stoichiometric mixture of calcium oxide, amorphous silica, alumina sol, and cobalt hydroxide at 200 °C. It was found that the catalyst consisted of Co3O4, CaO, and mayenite and exhibited a high activity for the combustion of propylene, benzene, and toluene at temperatures below 300 °C.
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Y. M. Kang and B. Z. Wan, Appl. Catal. A114 (1994) 35.
R. S. Drago, K. Jurczyk, D. L. Singh and V. Young, Appl. Catal. B8 (1996) 155.
N. Watanabe, H. Yamashita, H. Miyadera and S. Tominaga, Appl. Catal. B8 (1996) 405.
G. A. Lager, T. Armbruster and J. Faber, Amer. Mineral. 72 (1987) 756.
G. R. Rossman and D. R. Aines, Amer. Mineral. 76 (1991) 1153.
G. A. Lager and R. B. Dreele, Amer. Mineral. 81 (1996) 10.
F. Cavani, F. Trifiro and A. Vaccari, Catal. Today 11 (1991) 173.
B. Chen and J. L. Falconer, J. Catal. 144 (1993) 214.
S. Velu, R. Veda, A. Ramani, B. M. Chenda and S. Sivasanker, Chem. Commun. (1997) 2107.
S. Velu, K. Suzuki, M. P. Kapoor, F. Ohashi and T. Osaki, Appl. Catal. A213 (2001) 47.
S. Velu, K. Suzuki and T. Osaki, Catal. Lett. 69 (2000) 43.
R. D. Shannon, Acta Cryst. A32 (1976) 751.
H. Hosono and Y. Abe, Inorg. Chem. 26 (1987) 1192.
M. Lacerda, J. T. S. Irvine, F. P. Glasser and A. R. West, Nature 332 (1988) 525.
K. Hayashi, M. Hirano, S. Matsuishi and H. Hosono, J. Am. Chem. Soc. 124 (2002) 738.
S. Fujita, K. Suzuki, M. Ohkawa, Y. Miwa, Y. Iida, H. Masuda, S. Shimada and T. Mori, Chem. Mater. (in press).
J. H. Lunsford, Adv. Catal. 22 (1972) 265.
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Fujita, S., Suzuki, K. & Mori, T. Preparation of High-Performance Co3O4 Catalyst for Hydrocarbon Combustion from Co-Containing Hydrogarnet. Catalysis Letters 86, 139–144 (2003). https://doi.org/10.1023/A:1022679529612
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DOI: https://doi.org/10.1023/A:1022679529612